Evaluation of different strengthening methods in the mechanical and functional properties of soy protein-based bioplastics

被引:46
作者
Jimenez-Rosado, M. [1 ]
Bouroudian, E. [1 ]
Perez-Puyana, V. [2 ]
Guerrero, A. [1 ]
Romero, A. [2 ]
机构
[1] Univ Seville, Escuela Politecn Super, Dept Ingn Quim, Seville 41011, Spain
[2] Univ Seville, Dept Ingn Quim, Fac Quim, Seville 41012, Spain
关键词
Soy bioplastic; Pea bioplastic; Mold temperature; Dehydrothermal treatment; Ultrasounds; SUPERABSORBENT MATERIALS; CROSS-LINKING; PLASTICS; COMPOSITES; PERCEPTION; PRODUCTS; FIBERS; IMPACT; MEAT;
D O I
10.1016/j.jclepro.2020.121517
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
The bioplastics manufactured are still not competitive compared to conventional plastics, due to their higher price and poor mechanical properties. For this purpose, different physical strengthening methods have been studied to evaluate the reinforcement of soy protein-based bioplastics: mold temperature increase (from 70 degrees C to 130 degrees C), as the application of a dehydrothermal (4 and 24 h at 50 degrees C) or ultrasound (for 5 and 45 min at 20 kHz) treatment. In this sense, the crosslinking degree, the mechanical properties, water uptake measurements and scanning electron micrographs of the different bioplastics were compared. The results conclude that suitable processing conditions and post-treatments could favor some characteristics of bioplastics (such as maximum stress (similar to 5 times) or strain at break (similar to 3 times)), although worsening others (such as water uptake capacity (similar to 50%)). Specifically, thermal treatments improved the mechanical properties of the structures obtained, whereas the ultrasound treatment leads to the formation of a structure with smaller pores. (C) 2020 Elsevier Ltd. All rights reserved.
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页数:7
相关论文
共 46 条
[1]   Biodegradation of plastics: current scenario and future prospects for environmental safety [J].
Ahmed, Temoor ;
Shahid, Muhammad ;
Azeem, Farrukh ;
Rasul, Ijaz ;
Shah, Asad Ali ;
Noman, Muhammad ;
Hameed, Amir ;
Manzoor, Natasha ;
Manzoor, Irfan ;
Muhammad, Sher .
ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH, 2018, 25 (08) :7287-7298
[2]   Development of green superabsorbent materials from a by-product of the meat industry [J].
Alvarez-Castillo, Estefania ;
Bengoechea, Carlos ;
Rodriguez, Natalia ;
Guerrero, Antonio .
JOURNAL OF CLEANER PRODUCTION, 2019, 223 :651-661
[3]   Optimization of a thermal process for the production of superabsorbent materials based on a soy protein isolate [J].
Alvarez-Castillo, Estefania ;
Del Toro, Alejandro ;
Manuel Aguilar, Jose ;
Guerrero, Antonio ;
Bengoechea, Carlos .
INDUSTRIAL CROPS AND PRODUCTS, 2018, 125 :573-581
[4]   Sustainability of bio-based plastics: general comparative analysis and recommendations for improvement [J].
Alvarez-Chavez, Clara Rosalia ;
Edwards, Sally ;
Moure-Eraso, Rafael ;
Geiser, Kenneth .
JOURNAL OF CLEANER PRODUCTION, 2012, 23 (01) :47-56
[5]  
[Anonymous], NEW PLAST EC RETH FU
[6]  
[Anonymous], 2019, GUARD
[7]  
[Anonymous], COMMISSIONS CIRCULAR
[8]  
[Anonymous], USE HIGH POWER ULTRA
[9]   Marketing a new generation of bio-plastics products for a circular economy: The role of green self-identity, self-congruity, and perceived value [J].
Confente, Ilenia ;
Scarpi, Daniele ;
Russo, Ivan .
JOURNAL OF BUSINESS RESEARCH, 2020, 112 :431-439
[10]   Natural superabsorbent plastic materials based on a functionalized soy protein [J].
Cuadri, A. A. ;
Romero, A. ;
Bengoechea, C. ;
Guerrero, A. .
POLYMER TESTING, 2017, 58 :126-134