Controllable and facile synthesis of CsPbBr3-Cs4PbBr6 perovskite composites in pure polar solvent

被引:46
作者
Lou, Sunqi [1 ,2 ]
Xuan, Tongtong [2 ]
Liang, Qiongyun [2 ]
Huang, Junjian [2 ]
Cao, Luyu [2 ]
Yu, Caiyan [1 ]
Cao, Mengmeng [1 ]
Xia, Chao [1 ]
Wang, Jing [2 ]
Zhang, Dafeng [3 ]
Li, Huili [1 ]
机构
[1] East China Normal Univ, Sch Phys & Mat Sci, Minist Educ, Engn Res Ctr Nanophoton & Adv Instrument, Shanghai 200062, Peoples R China
[2] Sun Yat Sen Univ, State Key Lab Optoelect Mat & Technol, Key Lab Bioinorgan & Synthet Chem,Minist Educ, Sch Chem,Sch Mat Sci & Engn, Guangzhou 510275, Guangdong, Peoples R China
[3] Liaocheng Univ, Sch Mat Sci & Engn, Liaocheng 252000, Shandong, Peoples R China
基金
中国国家自然科学基金;
关键词
Perovskite; Luminescent; Morphology; Micropetals; QUANTUM DOTS; OPTICAL-PROPERTIES; I NANOCRYSTALS; CS4PBX6; X; TRANSFORMATION; BR; CL; PHOTOLUMINESCENCE;
D O I
10.1016/j.jcis.2018.11.041
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Here, we present a single atomic supersaturated recrystallization method to synthesize the green-emitting CsPbBr3-Cs4PbBr6 perovskite composites in solid state with the highest PLQY of 40.8% in pure polar solvent. The component, morphology, and optical properties of the microcrystals can be tuned by varying growth time, the content of ammonium bromide, and bromine source. The developed method provides a new route to large-scale synthesize high quality perovskite composites emitters for light-emitting diodes. (C) 2018 Elsevier Inc. All rights reserved.
引用
收藏
页码:384 / 388
页数:5
相关论文
共 32 条
  • [11] All Inorganic Halide Perovskites Nanosystem: Synthesis, Structural Features, Optical Properties and Optoelectronic Applications
    Li, Xiaoming
    Cao, Fei
    Yu, Dejian
    Chen, Jun
    Sun, Zhiguo
    Shen, Yalong
    Zhu, Ying
    Wang, Lin
    Wei, Yi
    Wu, Ye
    Zeng, Haibo
    [J]. SMALL, 2017, 13 (09)
  • [12] Composite Perovskites of Cesium Lead Bromide for Optimized Photoluminescence
    Ling, Yichuan
    Tan, Lei
    Wang, Xi
    Zhou, Yan
    Xin, Yan
    Ma, Biwu
    Hanson, Kenneth
    Gao, Hanwei
    [J]. JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2017, 8 (14): : 3266 - 3271
  • [13] Synergetic Effect of Postsynthetic Water Treatment on the Enhanced Photoluminescence and Stability of CsPbX3 (X = Cl, Br, I) Perovskite Nanocrystals
    Liu, Ying
    Li, Fei
    Liu, Quanlin
    Xia, Zhiguo
    [J]. CHEMISTRY OF MATERIALS, 2018, 30 (19) : 6922 - 6929
  • [14] Ligand Mediated Transformation of Cesium Lead Bromide Perovskite Nanocrystals to Lead Depleted Cs4PbBr6 Nanocrystals
    Liu, Zeke
    Bekenstein, Yehonadav
    Ye, Xingchen
    Nguyen, Son C.
    Swabeck, Joseph
    Zhang, Dandan
    Lee, Shuit-Tong
    Yang, Peidong
    Ma, Wanli
    Alivisatos, A. Paul
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2017, 139 (15) : 5309 - 5312
  • [15] Nanocomposites of CsPbBr3 perovskite nanocrystals in an ammonium bromide framework with enhanced stability
    Lou, Sunqi
    Xuan, Tongtong
    Yu, Caiyan
    Cao, Mengmeng
    Xia, Chao
    Wang, Jing
    Li, Huili
    [J]. JOURNAL OF MATERIALS CHEMISTRY C, 2017, 5 (30) : 7431 - 7435
  • [16] Changing the Dimensionality of Cesium Lead Bromide Nanocrystals by Reversible Postsynthesis Transformations with Amines
    Palazon, Francisco
    Almeida, Guilherme
    Akkerman, Quinten A.
    De Trizio, Luca
    Dang, Zhiya
    Prato, Mirko
    Manna, Liberato
    [J]. CHEMISTRY OF MATERIALS, 2017, 29 (10) : 4167 - 4171
  • [17] Highly Emissive Green Perovskite Nanocrystals in a Solid State Crystalline Matrix
    Quan, Li Na
    Quintero-Bermudez, Rafael
    Voznyy, Oleksandr
    Walters, Grant
    Jain, Ankit
    Fan, James Zhangming
    Zheng, Xueli
    Yang, Zhenyu
    Sargent, Edward H.
    [J]. ADVANCED MATERIALS, 2017, 29 (21)
  • [18] Pure Cs4PbBr6: Highly Luminescent Zero Dimensional Perovskite Solids
    Saidaminov, Makhsud I.
    Almutlaq, Jawaher
    Sarmah, Smritakshi
    Dursun, Ibrahim
    Zhumekenov, Ayan A.
    Begum, Raihana
    Pan, Jun
    Cho, Namchul
    Mohammed, Omar F.
    Bakr, Osman M.
    [J]. ACS ENERGY LETTERS, 2016, 1 (04): : 840 - 845
  • [19] Photoluminescence of Zero-Dimensional Perovskites and Perovskite-Related Materials
    Seth, Sudipta
    Samanta, Anunay
    [J]. JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2018, 9 (01): : 176 - 183
  • [20] Fluorescent Phase-Pure Zero-Dimensional Perovskite-Related Cs4PbBr6 Microdisks: Synthesis and Single-Particle Imaging Study
    Seth, Sudipta
    Samanta, Anunay
    [J]. JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2017, 8 (18): : 4461 - 4467