Dirty H2 Molecular Clusters as the DIB Sources: Spectroscopic and Physical Properties

We propose that the diffuse interstellar bands (DIBs) arise from absorption lines of electronic transitions in molecular clusters primarily composed of a single molecule, atom, or ion ("seed"), embedded in a single-layer shell of H-2 molecules (Bernstein et al. 2013). Less abundant variants of the cluster, including two seed molecules and/or a two-layer shell of H-2 molecules may also occur. The lines are broadened, blended, and wavelength-shifted by interactions between the seed and surrounding H-2 shell. We refer to these clusters as CHCs (Contaminated H-2 Clusters). CHC spectroscopy matches the diversity of observed DIB spectral profiles, and provides good fits to several DIB profiles based on a rotational temperature of 10 K. CHCs arise from similar to cm-sized, dirty H-2 ice balls, called CHIMPs (Contaminated H-2 Ice Macro-Particles), formed in cold, dense, Giant Molecular Clouds (GMCs), and later released into the interstellar medium (ISM) upon GMC disruption. Attractive interactions, arising from Van der Waals and ion-induced dipole potentials, between the seeds and H-2 molecules enable CHIMPs to attain cm-sized dimensions. When an ultraviolet (UV) photon is absorbed in the outer layer of a CHIMP, it heats the icy matrix and expels CHCs into the ISM. While CHCs are quickly destroyed by absorbing UV photons, they are replenished by the slowly eroding CHIMPs. Since CHCs require UV photons for their release, they are most abundant at, but not limited to, the edges of UV-opaque molecular clouds, consistent with the observed, preferred location of DIBs. An inherent property of CHCs, which can be characterized as nanometer size, spinning, dipolar dust grains, is that they emit in the radio-frequency region. Thus, CHCs offer a natural explanation to the anomalous microwave emission (AME) feature in the similar to 10-100 GHz spectral region.