Development of Ni-Based Catalysts for Steam Reforming of Tar Derived from Biomass Pyrolysis

被引:82
作者
Li, Dalin [1 ,2 ]
Nakagawa, Yoshinao [1 ]
Tomishige, Keiichi [1 ]
机构
[1] Tohoku Univ, Sch Engn, Dept Appl Chem, Sendai, Miyagi 9808579, Japan
[2] Fuzhou Univ, Natl Engn Res Ctr Chem Fertilizer Catalyst, Fuzhou 350002, Fujian, Peoples R China
基金
日本科学技术振兴机构;
关键词
steam reforming; tar; biomass; nickel; ceria; manganese oxide; platinum; magnesia; SOLID-SOLUTION CATALYSTS; SELF-REGENERATIVE ACTIVITY; FLUIDIZED-BED REACTOR; SHUT-DOWN OPERATION; DAILY START-UP; LOW-TEMPERATURE; PARTIAL OXIDATION; NOBLE-METALS; NI/MG(AL)O CATALYSTS; RH/CEO2/SIO2; CATALYSTS;
D O I
10.1016/S1872-2067(11)60359-8
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Nickel catalysts are effective for the steam reforming of tar derived from biomass pyrolysis, but the improvement is needed in terms of activity, stability, suppression of coke deposition and aggregation, and regeneration. Our recent development of Ni-based catalysts for the steam reforming of tar is reviewed including the modification with CeO2 (or MnO), trace Pt, and MgO. The role of additives such as CeO2, MnO, Pt, and MgO is also discussed.
引用
收藏
页码:583 / 594
页数:12
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