Nonclassical oxygen atom transfer reactions of oxomolybdenum(VI) bis(catecholate)

被引：23
|
作者：
Marshall-Roth, Travis [1 ]
Liebscher, Sean C. [1 ]
Rickert, Karl [1 ]
Seewald, Nicholas J. [1 ]
Oliver, Allen G. [1 ]
Brown, Seth N. [1 ]
机构：
[1] Univ Notre Dame, Dept Chem & Biochem, Notre Dame, IN 46556 USA
来源：
CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 63期
基金：
美国国家科学基金会;
关键词：
COUPLED ELECTRON-TRANSFER; OXO-TRANSFER-REACTION; REDOX-ACTIVE LIGANDS; MOLECULAR-OXYGEN; METAL-LIGAND; COMPLEXES; MOLYBDENUM; REACTIVITY; OXIDE; PYRIDINE;
D O I：
10.1039/c2cc33523a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Mechanistic studies indicate that the oxomolybdenum(VI) bis(3,5-di-tert-butylcatecholate) fragment deoxygenates pyridine-N-oxides in a reaction where the oxygen is delivered to molybdenum but the electrons for substrate reduction are drawn from the bound catecholate ligands, forming 3,5-di-tert-butyl-1,2-benzoquinone.
引用
收藏
页码：7826 / 7828
页数：3
相关论文
共 50 条
  • [1] Nonclassical oxygen atom transfer reactions of an eight-coordinate dioxomolybdenum(vi) complex
    Ranis, Leila G.
    Gianino, Jacqueline
    Hoffman, Justin M.
    Brown, Seth N.
    INORGANIC CHEMISTRY FRONTIERS, 2021, 8 (11) : 2865 - 2870
  • [2] Kinetic and Computational Studies of Rhenium Catalysis for Oxygen Atom Transfer Reactions
    Ibdah, Abdellatif
    Bakar, Heba Bani
    Alduwikat, Salwa
    AUSTRALIAN JOURNAL OF CHEMISTRY, 2018, 71 (2-3) : 149 - 159
  • [3] Kinetic studies of oxygen atom transfer reactions from trans-dioxoruthenium(VI) porphyrins to sulfides
    Abebrese, Chris
    Huang, Yan
    Pan, Alice
    Yuan, Zhibo
    Zhang, Rui
    JOURNAL OF INORGANIC BIOCHEMISTRY, 2011, 105 (12) : 1555 - 1561
  • [4] Substituent Effect on Oxygen Atom Transfer Reactivity from Oxomolybdenum Centers: Synthesis, Structure, Electrochemistry, and Mechanism
    Basu, Partha
    Nemykin, Victor N.
    Sengar, Raghvendra S.
    INORGANIC CHEMISTRY, 2009, 48 (13) : 6303 - 6313
  • [5] Oxygen Atom Transfer Reactions of Colloidal Metal Oxide Nanoparticles
    Lee, Justin L.
    Gentry, Noreen Elizabeth
    Peper, Jennifer L.
    Hetzel, Staci
    Quist, Christine
    Menges, Fabian S.
    Mayer, James M.
    ACS NANO, 2025, 19 (10) : 10289 - 10300
  • [6] Oxygen atom transfer catalysis by dioxidomolybdenum(VI) complexes of pyridyl aminophenolate ligands
    Hossain, Md Kamal
    Schachner, Joerg A.
    Haukka, Matti
    Richmond, Michael G.
    Moesch-Zanetti, Nadia C.
    Lehtonen, Ari
    Nordlander, Ebbe
    POLYHEDRON, 2021, 205
  • [7] Oxygen atom transfer catalysis: Ligand effects on the key reaction barrier in molybdenum (VI) dioxo systems
    Keith, Jason M.
    Tomic, Zoran D.
    Zaric, Snezana D.
    Hall, Michael B.
    JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2010, 324 (1-2) : 15 - 23
  • [8] The Metal or the Ligand? The Preferred Locus for Redox Changes in Oxygen Atom Transfer Reactions of Rhenium Amidodiphenoxides
    Hoffman, Justin M.
    Oliver, Allen G.
    Brown, Seth N.
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2017, 139 (12) : 4521 - 4531
  • [9] Oxygen-atom-transfer Reactions of a Palladium(II) Peroxocarbonate Complex
    Sase, Shohei
    Hashimoto, Maki
    Goto, Kei
    CHEMISTRY LETTERS, 2015, 44 (02) : 157 - 159
  • [10] Nitrogen oxyanion deoxygenation: Redox chemistry and oxygen atom transfer reactions
    Tran, Bao
    Smith, Jeremy
    COORDINATION CHEMISTRY REVIEWS, 2025, 530
12345