Nonclassical oxygen atom transfer reactions of oxomolybdenum(VI) bis(catecholate)

被引：22

作者：

Marshall-Roth, Travis ^{[1
]}

Liebscher, Sean C. ^{[1
]}

Rickert, Karl ^{[1
]}

Seewald, Nicholas J. ^{[1
]}

Oliver, Allen G. ^{[1
]}

Brown, Seth N. ^{[1
]}

机构：

[1] Univ Notre Dame, Dept Chem & Biochem, Notre Dame, IN 46556 USA

来源：

CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 63期

基金：

美国国家科学基金会;

关键词：

COUPLED ELECTRON-TRANSFER; OXO-TRANSFER-REACTION; REDOX-ACTIVE LIGANDS; MOLECULAR-OXYGEN; METAL-LIGAND; COMPLEXES; MOLYBDENUM; REACTIVITY; OXIDE; PYRIDINE;

D O I：

10.1039/c2cc33523a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Mechanistic studies indicate that the oxomolybdenum(VI) bis(3,5-di-tert-butylcatecholate) fragment deoxygenates pyridine-N-oxides in a reaction where the oxygen is delivered to molybdenum but the electrons for substrate reduction are drawn from the bound catecholate ligands, forming 3,5-di-tert-butyl-1,2-benzoquinone.

引用

页码：7826 / 7828

页数：3

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