Visible-Light-Promoted Stereoselective Alkylation by Combining Heterogeneous Photocatalysis with Organocatalysis

被引：233

作者：

Cherevatskaya, Maria ^{[1
]}

Neumann, Matthias ^{[1
]}

Fueldner, Stefan ^{[1
]}

Harlander, Christoph ^{[1
]}

Kuemmel, Susanne ^{[1
]}

Dankesreiter, Stephan ^{[1
]}

Pfitzner, Arno ^{[1
]}

Zeitler, Kirsten ^{[1
]}

Koenig, Burkhard ^{[1
]}

机构：

[1] Univ Regensburg, Fak Chem & Pharm, D-93040 Regensburg, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2012年 / 51卷 / 17期

关键词：

alkylation; organocatalysis; photocatalysis; semiconductors; visible light; TITANIUM-DIOXIDE NANOMATERIALS; C-H FUNCTIONALIZATION; PHOTOREDOX CATALYSIS; SEMICONDUCTOR PHOTOCATALYSIS; WATER; TIO2; OXIDATION; ALDEHYDES; HYDROGEN; TRIFLUOROMETHYLATION;

D O I：

10.1002/anie.201108721

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Dream team: Heterogeneous inorganic semiconductors and chiral organocatalysts team up for the stereoselective photocatalytic formation of carbon-carbon bonds. However, the connection between the organic and inorganic catalysts should not be too tight: Covalent immobilization inactivates the system. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：4062 / 4066

页数：5

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