Chiral Dirhodium Catalysts: A New Era for Asymmetric Catalysis

被引：21

作者：

El-Deftar, Moteaa ^{[1
]}

Adly, Frady. G. ^{[1
]}

Gardiner, Michael G. ^{[2
]}

Ghanem, Ashraf ^{[1
]}

机构：

[1] Univ Canberra, Fac Appl Sci, Chiral Program, Bruce, ACT 2601, Australia

[2] Univ Tasmania, Sch Chem, Hobart, Tas 7011, Australia

来源：

CURRENT ORGANIC CHEMISTRY | 2012年 / 16卷 / 15期

关键词：

Dirhodium catalysts; Asymmetric catalysis; Stereoselrctive reactions; Enantioselectivity; Homogenous catalysts; Chiral catalysts; C-H INSERTION; HOST-GUEST COMPLEXATION; ALPHA-AMINO-ACIDS; ENANTIOSELECTIVE CYCLOPROPANATION; INTRAMOLECULAR CYCLOPROPANATIONS; IODONIUM YLIDES; 1,3-DIPOLAR CYCLOADDITION; STEREOSELECTIVE-SYNTHESIS; CARBOXAMIDATE CATALYST; PHENYLIODONIUM YLIDES;

D O I：

10.2174/138527212802651368

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The catalysis by dirhodium paddlewheel complexes has been an area of immense interest and extensive study over the past three decades - not only because most of the catalysts are highly stable to heat, moisture and ambient atmosphere but also for the asymmetric induction in the ylide generation. In this review, we attempt to provide an overview on the general preparation method for most homogeneous chiral dirhodium(II) catalysts that have appeared to date and their recent applications in asymmetric catalysis with iodonium ylides as carbenoid precursors.

引用

页码：1808 / 1836

页数：29

共 161 条

[11] ASYMMETRIC CATALYSIS .58. ENANTIOSELECTIVE S-H AND C-H INSERTIONS WITH OPTICALLY-ACTIVE RH(II) AND CU(II) CATALYSTS [J].

BRUNNER, H ;

WUTZ, K ;

DOYLE, MP .

MONATSHEFTE FUR CHEMIE, 1990, 121 (10) :755-764

[12] Asymmetric rhodium carbenoid insertion into the Si-H bond [J].

Buck, RT ;

Doyle, MP ;

Drysdale, MJ ;

Ferris, L ;

Forbes, DC ;

Haigh, D ;

Moody, CJ ;

Pearson, ND ;

Zhou, QL .

TETRAHEDRON LETTERS, 1996, 37 (42) :7631-7634

[13] RHODIUM(II)2,4,6-TRIARYLBENZOATES - IMPROVED CATALYSTS FOR THE SYN CYCLOPROPANATION OF Z-OLEFINS [J].

CALLOT, HJ ;

METZ, F .

TETRAHEDRON, 1985, 41 (20) :4495-4501

[14] A phenyliodonium ylide as a precursor for dicarboethoxycarbene: Demonstration of a strategy for carbene generation [J].

Camacho, MB ;

Clark, AE ;

Liebrecht, TA ;

DeLuca, JP .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (21) :5210-5211

[15] STRUCTURAL AND ELECTROCHEMICAL CHARACTERIZATION OF THE NOVEL ORTHO-METALATED DIRHODIUM(II) COMPOUNDS RH2(O2CCH3)2[(C6H5)2P(C6H4)]2.2L [J].

CHAKRAVARTY, AR ;

COTTON, FA ;

TOCHER, DA ;

TOCHER, JH .

ORGANOMETALLICS, 1985, 4 (01) :8-13

[16] ORTHO-METALLATION AT DIMETALLIC CENTERS - SYNTHESES AND X-RAY CHARACTERIZATIONS OF OS2(O2CME)2[PH2P(C6H4)]2CL2 AND RH2(O2CME)2[PH2P(C6H4)]2(2MECO2H) [J].

CHAKRAVARTY, AR ;

COTTON, FA ;

TOCHER, DA .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1984, (08) :501-502

[17]

Chernyaevs II, 1960, RUSS J INORG CHEM, V5, P559

[18] Studies in catalytic C-H amination involving nitrene C-H insertion [J].

Collet, Florence ;

Lescot, Camille ;

Liang, Chungen ;

Dauban, Philippe .

DALTON TRANSACTIONS, 2010, 39 (43) :10401-10413

[19] Stereoselective Rhodium-Catalyzed Imination of Sulfides [J].

Collet, Florence ;

Dodd, Robert H. ;

Dauban, Philippe .

ORGANIC LETTERS, 2008, 10 (23) :5473-5476

[20] PREPARATION AND STRUCTURE OF CRYSTALLINE TETRAKIS(D-MANDELATO)DIMOLYBDENUM(II) BIS(TETRAHYDROFURANATE) [J].

COTTON, FA ;

FALVELLO, LR ;

MURILLO, CA .

INORGANIC CHEMISTRY, 1983, 22 (03) :382-387

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