Chiral Dirhodium Catalysts: A New Era for Asymmetric Catalysis

被引：21

作者：

El-Deftar, Moteaa ^{[1
]}

Adly, Frady. G. ^{[1
]}

Gardiner, Michael G. ^{[2
]}

Ghanem, Ashraf ^{[1
]}

机构：

[1] Univ Canberra, Fac Appl Sci, Chiral Program, Bruce, ACT 2601, Australia

[2] Univ Tasmania, Sch Chem, Hobart, Tas 7011, Australia

来源：

CURRENT ORGANIC CHEMISTRY | 2012年 / 16卷 / 15期

关键词：

Dirhodium catalysts; Asymmetric catalysis; Stereoselrctive reactions; Enantioselectivity; Homogenous catalysts; Chiral catalysts; C-H INSERTION; HOST-GUEST COMPLEXATION; ALPHA-AMINO-ACIDS; ENANTIOSELECTIVE CYCLOPROPANATION; INTRAMOLECULAR CYCLOPROPANATIONS; IODONIUM YLIDES; 1,3-DIPOLAR CYCLOADDITION; STEREOSELECTIVE-SYNTHESIS; CARBOXAMIDATE CATALYST; PHENYLIODONIUM YLIDES;

D O I：

10.2174/138527212802651368

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The catalysis by dirhodium paddlewheel complexes has been an area of immense interest and extensive study over the past three decades - not only because most of the catalysts are highly stable to heat, moisture and ambient atmosphere but also for the asymmetric induction in the ylide generation. In this review, we attempt to provide an overview on the general preparation method for most homogeneous chiral dirhodium(II) catalysts that have appeared to date and their recent applications in asymmetric catalysis with iodonium ylides as carbenoid precursors.

引用

页码：1808 / 1836

页数：29

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