Toward aceneporphyrinoids: synthesis and transformations of palladium(II) meso-anthriporphyrin

被引：37
作者：
Szyszko, Bartosz [1 ]
Latos-Grazynski, Lechoslaw [1 ]
Szterenberg, Ludmila [1 ]
机构：
[1] Univ Wroclaw, Dept Chem, PL-50383 Wroclaw, Poland
来源：
CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 41期
关键词：
MEDIATED CONTRACTION; CRYSTAL-STRUCTURE; COMPLEXES; BENZIPORPHYRINS; BENZENE;
D O I：
10.1039/c2cc30362k
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
meso-Anthriporphyrin is a carbaporphyrinoid with an anthracene ring embedded in the tripyrrolic framework. The coordination of palladium(II) results in a specific intramacrocyclic metal(II)-eta(2)-CC interaction which facilitates the cleavage to palladium(II) acyclic oligopyrrole with the appended anthracene moiety.
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收藏
页码：5004 / 5006
页数：3
相关论文
共 17 条
  • [1] Intramolecular and interionic structural studies of novel olefin palladium(II) and platinum(II) complexes containing poly(pyrazol-1-yl)borate and -methane ligands. X-ray structures of palladium five-coordinate complexes
    Binotti, B
    Bellachioma, G
    Cardaci, G
    Macchioni, A
    Zuccaccia, C
    Foresti, E
    Sabatino, P
    [J]. ORGANOMETALLICS, 2002, 21 (02) : 346 - 354
  • [2] One compound, two structures:: synthesis, structures and reactivity of a novel (tripyrrinato)palladium(II) trifluoracetate complex TrpyPdOAcf
    Bröring, M
    Brandt, CD
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2002, (07): : 1391 - 1395
  • [3] Organometallic palladium and platinum complexes with strongly donating alkyl coligands - Synthesis, structures, chemical and cytotoxic properties
    Klein, Axel
    Luening, Anna
    Ott, Ingo
    Hamel, Laura
    Neugebauer, Michael
    Butsch, Katharina
    Lingen, Verena
    Heinrich, Frank
    Elmas, Said
    [J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2010, 695 (15-16) : 1898 - 1905
  • [4] Naphthiporphyrins
    Lash, Timothy D.
    Young, Alexandra M.
    Rasmussen, Jane M.
    Ferrence, Gregory M.
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 2011, 76 (14) : 5636 - 5651
  • [5] SYNTHESIS, ELECTROCHEMISTRY, AND CRYSTAL-STRUCTURE OF N,N'-DICYANOQUINONEDIIMINE (DCNQI) DERIVATIVES CONTAINING FUSED BENZENE RINGS
    MARTIN, N
    NAVARRO, JA
    SEOANE, C
    ALBERT, A
    CANO, FH
    BECKER, JY
    KHODORKOVSKY, V
    HARLEV, E
    HANACK, M
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 1992, 57 (21) : 5726 - 5730
  • [6] Palladium vacataporphyrin reveals conformational rearrangements involving Huckel and Mobius macrocyclic topologies
    Pacholska-Dudziak, Ewa
    Skonieczny, Janusz
    Pawlicki, Milosz
    Szterenberg, Ludmila
    Ciunik, Zbigniew
    Latos-Graynski, Lechostaw
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (19) : 6182 - 6195
  • [7] Pawlicki M., 2010, HDB PORPHYRIN SCI AP, P104
  • [8] 1,4-DIMETHYL-9,10-ANTHRAQUINODIMETHANE - MOLECULAR AND CRYSTAL-STRUCTURE OF A SIMPLE QUINODIMETHANE
    ROSENFELD, S
    JASINSKI, JP
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 1991, 56 (02) : 878 - 880
  • [9] Tetraphenyl-p-benziporphyrin:: A carbaporphyrinoid with two linked carbon atoms in the coordination core
    Stepien, M
    Latos-Grazynski, L
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (15) : 3838 - 3839
  • [10] Cadmium(II) and nickel(II) complexes of benziporphyrins. A study of weak intramolecular metal-arene interactions
    Stepien, M
    Latos-Grazynski, L
    Szterenberg, L
    Panek, J
    Latajka, Z
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (14) : 4566 - 4580
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