Experimental and computational investigations of the properties of fluorinated single-walled carbon nanotubes

被引：62
作者：
Bettinger, HF [1 ]
机构：
[1] Ruhr Univ Bochum, Lehrstuhl Organ Chem 2, D-44780 Bochum, Germany
来源：
CHEMPHYSCHEM | 2003年 / 4卷 / 12期
关键词：
density functional calculations; fluorine; nanotubes; solubility; thermochemistry;
D O I：
10.1002/cphc.200300854
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Fluorination of single-walled carbon nanotubes by reaction with elemental fluorine at elevated temperatures provides fluorinated single-walled carbon nonotubes (F-SWNT), which have the highest degree of functionalization (up to F/C= 1/2) of any derivatized carbon-nanotube material reported to dote. Also, F-SWNTs have received more scrutiny than any other functionalized carbon nanotubes. This Minireview covers experimental and computational investigations of F-SWNTs with a focus on the nature and the strength of the C-F linkage.
引用
收藏
页码：1283 / 1289
页数：7
相关论文
共 96 条
[61]   Surface properties of fluorinated single-walled carbon nanotubes [J].
Lee, YS ;
Cho, TH ;
Lee, BK ;
Rho, JS ;
An, KH ;
Lee, YH .
JOURNAL OF FLUORINE CHEMISTRY, 2003, 120 (02) :99-104
[62]   A spectroscopic study of the fluorination and defluorination reactions on single-walled carbon nanotubes [J].
Marcoux, PR ;
Schreiber, J ;
Batail, P ;
Lefrant, S ;
Renouard, J ;
Jacob, G ;
Albertini, D ;
Mevellec, JY .
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2002, 4 (11) :2278-2285
[63]   Fluorination of single-wall carbon nanotubes [J].
Mickelson, ET ;
Huffman, CB ;
Rinzler, AG ;
Smalley, RE ;
Hauge, RH ;
Margrave, JL .
CHEMICAL PHYSICS LETTERS, 1998, 296 (1-2) :188-194
[64]   Solvation of fluorinated single-wall carbon nanotubes in alcohol solvents [J].
Mickelson, ET ;
Chiang, IW ;
Zimmerman, JL ;
Boul, PJ ;
Lozano, J ;
Liu, J ;
Smalley, RE ;
Hauge, RH ;
Margrave, JL .
JOURNAL OF PHYSICAL CHEMISTRY B, 1999, 103 (21) :4318-4322
[65]  
Nakajima T, 1996, EUR J SOL STATE INOR, V33, P831
[66]  
NAKAJIMA T, 1995, FLUORINE CARBON FLUI
[67]   Gas-phase catalytic growth of single-walled carbon nanotubes from carbon monoxide [J].
Nikolaev, P ;
Bronikowski, MJ ;
Bradley, RK ;
Rohmund, F ;
Colbert, DT ;
Smith, KA ;
Smalley, RE .
CHEMICAL PHYSICS LETTERS, 1999, 313 (1-2) :91-97
[68]   Chemistry of single-walled carbon nanotubes [J].
Niyogi, S ;
Hamon, MA ;
Hu, H ;
Zhao, B ;
Bhowmik, P ;
Sen, R ;
Itkis, ME ;
Haddon, RC .
ACCOUNTS OF CHEMICAL RESEARCH, 2002, 35 (12) :1105-1113
[69]   Reversible water-solubilization of single-walled carbon nanotubes by polymer wrapping [J].
O'Connell, MJ ;
Boul, P ;
Ericson, LM ;
Huffman, C ;
Wang, YH ;
Haroz, E ;
Kuper, C ;
Tour, J ;
Ausman, KD ;
Smalley, RE .
CHEMICAL PHYSICS LETTERS, 2001, 342 (3-4) :265-271
[70]   Fluorinated cage multiwall carbon nanoparticles [J].
Okotrub, AV ;
Yudanov, NF ;
Chuvilin, AL ;
Asanov, IP ;
Shubin, YV ;
Bulusheva, LG ;
Gusel'nikov, AV ;
Fyodorov, IS .
CHEMICAL PHYSICS LETTERS, 2000, 322 (3-4) :231-236
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