Experimental and computational investigations of the properties of fluorinated single-walled carbon nanotubes

被引:62
作者
Bettinger, HF [1 ]
机构
[1] Ruhr Univ Bochum, Lehrstuhl Organ Chem 2, D-44780 Bochum, Germany
关键词
density functional calculations; fluorine; nanotubes; solubility; thermochemistry;
D O I
10.1002/cphc.200300854
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Fluorination of single-walled carbon nanotubes by reaction with elemental fluorine at elevated temperatures provides fluorinated single-walled carbon nonotubes (F-SWNT), which have the highest degree of functionalization (up to F/C= 1/2) of any derivatized carbon-nanotube material reported to dote. Also, F-SWNTs have received more scrutiny than any other functionalized carbon nanotubes. This Minireview covers experimental and computational investigations of F-SWNTs with a focus on the nature and the strength of the C-F linkage.
引用
收藏
页码:1283 / 1289
页数:7
相关论文
共 96 条
[1]   Structural transformation of fluorinated carbon nanotubes induced by in situ electron-beam irradiation [J].
An, KH ;
Parka, KA ;
Heo, JG ;
Lee, JY ;
Jeon, KK ;
Lim, SC ;
Yang, CW ;
Lee, YS ;
Lee, YH .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (10) :3057-3061
[2]   X-ray photoemission spectroscopy study of fluorinated single-walled carbon nanotubes [J].
An, KH ;
Heo, JG ;
Jeon, KG ;
Bae, D ;
Jo, CS ;
Yang, CW ;
Park, CY ;
Lee, YH ;
Lee, YS ;
Chung, YS .
APPLIED PHYSICS LETTERS, 2002, 80 (22) :4235-4237
[3]   Functionalization of carbon nanotubes by electrochemical reduction of aryl diazonium salts: A bucky paper electrode [J].
Bahr, JL ;
Yang, JP ;
Kosynkin, DV ;
Bronikowski, MJ ;
Smalley, RE ;
Tour, JM .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (27) :6536-6542
[4]   Covalent chemistry of single-wall carbon nanotubes [J].
Bahr, JL ;
Tour, JM .
JOURNAL OF MATERIALS CHEMISTRY, 2002, 12 (07) :1952-1958
[5]   Highly functionalized carbon nanotubes using in situ generated diazonium compounds [J].
Bahr, JL ;
Tour, JM .
CHEMISTRY OF MATERIALS, 2001, 13 (11) :3823-+
[6]   Dissolution of small diameter single-wall carbon nanotubes in organic solvents? [J].
Bahr, JL ;
Mickelson, ET ;
Bronikowski, MJ ;
Smalley, RE ;
Tour, JM .
CHEMICAL COMMUNICATIONS, 2001, (02) :193-194
[7]  
Balavoine F, 1999, ANGEW CHEM INT EDIT, V38, P1912, DOI 10.1002/(SICI)1521-3773(19990712)38:13/14<1912::AID-ANIE1912>3.0.CO
[8]  
2-2
[9]  
BALAVOINE F, 1999, ANGEW CHEM, V111, P2036
[10]   Rational chemical strategies for carbon nanotube functionalization [J].
Banerjee, S ;
Kahn, MGC ;
Wong, SS .
CHEMISTRY-A EUROPEAN JOURNAL, 2003, 9 (09) :1899-1908