Chemistry of lanthanide-metal carbonyl systems: the ytterbium-chromium carbonyls interaction

被引:3
作者
Grillone, MD [1 ]
Addamo, M [1 ]
Volpe, M [1 ]
机构
[1] Univ Palermo, Dept Chem Engn Proc & Mat, I-90128 Palermo, Italy
关键词
chemical synthesis; heteronuclear metal carbonyls; lanthanide-transition metal carbonyls; ytterbium-chromium carbonyl compounds;
D O I
10.1016/S0925-8388(01)00986-0
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The interaction of the chromium carbonyl hydrides HCr2(CO)(10)(-) or HCr(CO)(5)(-) with Yb(acac)(3). 3H(2)O has been investigated, and the experimental conditions leading to the isolation of ytterbium-chromium carbonyl complex species are reported. Formulation of the coordination compounds produced by such interactions has been proposed on the basis of analytical data and IR spectroscopy. (C) 2001 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:61 / 65
页数:5
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