Catalytic reduction of NO by H2 over Ag/Al2O3 under dry reducing conditions

被引：6

作者：

Backman, H ^{[1
]}

Jensén, J ^{[1
]}

Klingstedt, F ^{[1
]}

Salmi, T ^{[1
]}

Murzin, DY ^{[1
]}

机构：

[1] Abo Akad Univ, Proc Chem Ctr, Lab Ind Chem, FIN-20500 Turku, Finland

来源：

APPLIED CATALYSIS A-GENERAL | 2005年 / 294卷 / 01期

关键词：

NO reduction; hydrogen; deuterium; Ag/Al2O3; isotopic exchange; transient step response;

D O I：

10.1016/j.apcata.2005.06.028

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The kinetics and mechanism of the reduction of NO and N2O by H-2 over Ag/Al2O3 were studied with transient step response and isotope exchange techniques, Dissociation of hydrogen and deuterium was observed on the Ag/alumina catalyst. The reduction of NO with hydrogen gave N-2 as the main product and N2O, NH3 and H2O as by-products, while the catalyst showed low activity for the self-decomposition of NO and N2O. To clarify the reaction mechanism for the reduction of NO with hydrogen parameter estimation and modeling was carried out. (c) 2005 Elsevier B.V. All rights reserved.

引用

页码：49 / 58

页数：10

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