Charge Carrier Dipole Traps in Neat Molecular Crystals of Polar Molecules

被引:0
作者
Skryshevski, Yu. [1 ]
Ostapenko, N. [1 ]
Kadashchuk, A. [1 ]
Sugakov, V. [2 ]
Izvekov, S. [2 ]
机构
[1] NAS, Inst Phys, UA-252022 Kiev, Ukraine
[2] NAS, Inst Nucl Res, UA-252022 Kiev, Ukraine
来源
MOLECULAR CRYSTALS AND LIQUID CRYSTALS SCIENCE AND TECHNOLOGY SECTION A-MOLECULAR CRYSTALS AND LIQUID CRYSTALS | 1998年 / 324卷
关键词
charge-carrier dipole traps; orientational defects; carbazole; thermoluminescence; electrostatic interaction; dipole moment;
D O I
10.1080/10587259808047141
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The charge-carrier traps in the neat carbazole crystal have been found and were interpreted as dipole traps formed by the intrinsic orientational crystalline defects appearing when a molecule is rotated by 180 degrees along the long in-plane axis as compared to the bulk molecules. The depths of trapping states established on the neighboring molecules of crystal in the vicinity of one, two and tree reoriented molecules was calculated. Energetic spectrum of dipole traps was studied by fractional thermoluminescence and the experimental results are in good agreement with calculation.
引用
收藏
页码:101 / 106
页数:6
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