Modelling complex organic molecules in dense regions: Eley-Rideal and complex induced reaction

被引:144
作者
Ruaud, M. [1 ,2 ]
Loison, J. C. [3 ,4 ]
Hickson, K. M. [3 ,4 ]
Gratier, P. [1 ,2 ]
Hersant, F. [1 ,2 ]
Wakelam, V. [1 ,2 ]
机构
[1] Univ Bordeaux, LAB, UMR 5804, F-33270 Floirac, France
[2] CNRS, LAB, UMR 5804, F-33270 Floirac, France
[3] Univ Bordeaux, ISM, UMR 5255, F-33400 Talence, France
[4] CNRS, ISM, UMR 5255, F-33400 Talence, France
关键词
astrochemistry; ISM: abundances; ISM: clouds; ISM: molecules; GAS-PHASE CHEMISTRY; CHEMICAL KINETIC DATABASE; ATOMIC CARBON; RATE-CONSTANT; AB-INITIO; ABSORPTION-SPECTROSCOPY; COMBUSTION CHEMISTRY; INTERSTELLAR CLOUDS; PRESSURE-DEPENDENCE; TUNNELING REACTIONS;
D O I
10.1093/mnras/stu2709
中图分类号
P1 [天文学];
学科分类号
0704 ;
摘要
Recent observations have revealed the existence of complex organic molecules (COMs) in cold dense cores and pre-stellar cores. The presence of these molecules in such cold conditions is not well understood and remains a matter of debate since the previously proposed 'warm-up' scenario cannot explain these observations. In this paper, we study the effect of Eley-Rideal and complex induced reaction mechanisms of gas-phase carbon atoms with the main ice components of dust grains on the formation of COMs in cold and dense regions. Based on recent experiments, we use a low value for the chemical desorption efficiency (which was previously invoked to explain the observed COM abundances). We show that our introduced mechanisms are efficient enough to produce a large amount of COMs in the gas phase at temperatures as low as 10 K.
引用
收藏
页码:4004 / 4017
页数:14
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