Creation of a monomeric ag species on the surface of γ-ZrP as an efficient heterogeneous catalyst for the selective oxidation of cycloolefins

被引：5

作者：

Liu, Junhua ^{[1
,2
]}

Wang, Fang ^{[1
,2
]}

Xu, Xianlun ^{[1
]}

机构：

[1] Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China

[2] Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China

来源：

CATALYSIS LETTERS | 2008年 / 120卷 / 1-2期

关键词：

allylic oxidation; cycloolefin; enols; silver; zirconium phosphates;

D O I：

10.1007/s10562-007-9259-6

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A hybrid complex Zr(PO4)(AgHPO4) was prepared by ion-exchange and its activity was examined on the allylic oxidation of cycloolefins using tert-butylhydroperoxide (TBHP) as oxidant under argon atmosphere. Under these reaction conditions, attack of the activated C-H bond was preferred instead of the epoxidation of C=C bond, yielding enols as the main products, this is a novel highly active/selective and reusable heterogeneous catalyst.

引用

页码：106 / 110

页数：5

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