Hierarchical silicalite-1 octahedra comprising highly-branched orthogonally-stacked nanoplates as efficient catalysts for vapor-phase Beckmann rearrangement

被引：32

作者：

Chang, Albert ^{[1
]}

Hsiao, Hsu-Ming ^{[1
]}

Chen, Tsai-Hsiu ^{[1
]}

Chu, Ming-Wen ^{[2
]}

Yang, Chia-Min ^{[1
,3
]}

机构：

[1] Natl Tsing Hua Univ, Dept Chem, Hsinchu 30013, Taiwan

[2] Natl Taiwan Univ, Ctr Condensed Matter Sci, Taipei 10617, Taiwan

[3] Natl Tsing Hua Univ, Frontier Res Ctr Fundamental & Appl Sci Matters, Hsinchu 30013, Taiwan

来源：

CHEMICAL COMMUNICATIONS | 2016年 / 52卷 / 80期

关键词：

MESOSTRUCTURED ZEOLITE NANOSHEETS; STRUCTURE-DIRECTING AGENTS; EPSILON-CAPROLACTAM; ACTIVE-SITES; MFI ZEOLITE; MESOPORES; SURFACTANTS; MICROPORES; GENERATION; MOLECULES;

D O I：

10.1039/c6cc05992a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A triblock structure-directing agent was designed to synthesize hierarchical silicalite-1 octahedra comprising highly-branched, orthogonally-stacked and self-pillared nanoplates that exhibited excellent and stable activity for the vapor-phase Beckmann rearrangement of cyclic oximes and high lactam selectivity.

引用

页码：11939 / 11942

页数：4

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