Selective conversion of glucose into lactic acid with immobilized ytterbium triflate

被引:10
作者
Wang Shiwei [1 ]
Wang Qibao [1 ]
机构
[1] China Univ Min & Technol Beijing, Sch Chem & Environm Engn, D11 Xueyuan Rd, Beijing 100083, Peoples R China
关键词
Ytterbium triflate; SBA-15; Glucose; Lactic acid; HYDROTHERMAL CONVERSION; METHYL LACTATE; CATALYTIC CONVERSION; CELLULOSE; BIOMASS; SBA-15; LEWIS; DECOMPOSITION; ZEOLITE; MN;
D O I
10.1007/s11144-018-1448-3
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Ytterbium triflate was immobilized on SBA-15 via chemical grafting and co-condensation and the catalytic performance of the immobilized ytterbium triflate for the selective conversion of glucose into lactic acid was investigated in this paper. The characterization results showed that ytterbium triflate was immobilized on SBA-15 successfully. It was found that the immobilized ytterbium triflate catalyst can catalyze the transformation of glucose into lactic acid effectively. The 58.01% yield of lactic acid was obtained from glucose at 200 degrees C. The HPLC analysis results of the products showed that the glyceraldehyde might act as an intermediate for the formation of lactic acid during the reaction. The immobilized ytterbium triflate catalyst was recycled for more than five times without noticeable loss in activity.
引用
收藏
页码:923 / 936
页数:14
相关论文
共 42 条
  • [1] Recent advances in lactic acid production by microbial fermentation processes
    Abdel-Rahman, Mohamed Ali
    Tashiro, Yukihiro
    Sonomoto, Kenji
    [J]. BIOTECHNOLOGY ADVANCES, 2013, 31 (06) : 877 - 902
  • [2] Domino Reaction Catalyzed by Zeolites with BrOnsted and Lewis Acid Sites for the Production of -Valerolactone from Furfural
    Bui, Linh
    Luo, Helen
    Gunther, William R.
    Roman-Leshkov, Yuriy
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2013, 52 (31) : 8022 - 8025
  • [3] Cellulose hydrothermal conversion promoted by heterogeneous Bronsted and Lewis acids: Remarkable efficiency of solid Lewis acids to produce lactic acid
    Chambon, Flora
    Rataboul, Franck
    Pinel, Catherine
    Cabiac, Amandine
    Guillon, Emmanuelle
    Essayem, Nadine
    [J]. APPLIED CATALYSIS B-ENVIRONMENTAL, 2011, 105 (1-2) : 171 - 181
  • [4] Macroporous organosilica films via a template-free photoinduced sol-gel process
    Chemtob, Abraham
    Peter, Mathieu
    Belon, Cindy
    Dietlin, Celine
    Croutxe-Barghorn, Celine
    Vidal, Loic
    Rigolet, Severinne
    [J]. JOURNAL OF MATERIALS CHEMISTRY, 2010, 20 (41) : 9104 - 9112
  • [5] Opportunities and challenges for a sustainable energy future
    Chu, Steven
    Majumdar, Arun
    [J]. NATURE, 2012, 488 (7411) : 294 - 303
  • [6] Study of SBA-15 supported catalysts for toluene and NO removal: the effect of promoters (Co, Ni, Mn, Ce)
    Chuang, Kui-Hao
    Liu, Zhen-Shu
    Chang, Yu-Hao
    Lu, Chi-Yuan
    Wey, Ming-Yen
    [J]. REACTION KINETICS MECHANISMS AND CATALYSIS, 2010, 99 (02) : 409 - 420
  • [7] Fast and Selective Sugar Conversion to Alkyl Lactate and Lactic Acid with Bifunctional Carbon-Silica Catalysts
    de Clippel, Filip
    Dusselier, Michiel
    Van Rompaey, Ruben
    Vanelderen, Pieter
    Dijkmans, Jan
    Makshina, Ekaterina
    Giebeler, Lars
    Oswald, Steffen
    Baron, Gino V.
    Denayer, Joeri F. M.
    Pescarmona, Paolo P.
    Jacobs, Pierre A.
    Sels, Bert F.
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (24) : 10089 - 10101
  • [8] Catalytic transformations of cellulose and cellulose-derived carbohydrates into organic acids
    Deng, Weiping
    Zhang, Qinghong
    Wang, Ye
    [J]. CATALYSIS TODAY, 2014, 234 : 31 - 41
  • [9] Fructose conversion in the presence of Sn(IV) catalysts exhibiting high selectivity to lactic acid
    dos Santos, Jailma Barros
    Araujo de Albuquerque, Nilson Jose
    de Paiva e Silva Zanta, Carmen Lucia
    Meneghetti, Mario Roberto
    Plentz Meneghetti, Simoni Margareti
    [J]. RSC Advances, 2015, 5 (110): : 90952 - 90959
  • [10] Lactic acid as a platform chemical in the biobased economy: the role of chemocatalysis
    Dusselier, Michiel
    Van Wouwe, Pieter
    Dewaele, Annelies
    Makshina, Ekaterina
    Sels, Bert F.
    [J]. ENERGY & ENVIRONMENTAL SCIENCE, 2013, 6 (05) : 1415 - 1442