Dichlorido{2-[(thiophen-2-ylmethyl)iminomethyl]pyridine-κ2N,N′}palladium(II)

被引:3
|
作者
Onani, Martin O. [1 ]
Motswainyana, William M. [1 ]
机构
[1] Univ Western Cape, ZA-7535 Bellville, South Africa
来源
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2011年 / 67卷
关键词
PALLADIUM COMPLEXES SYNTHESIS; MOLECULAR-STRUCTURES; ETHYLENE;
D O I
10.1107/S1600536811037214
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the title compound, [PdCl2(C11H10N2S)], the Pd-II ion is four-coordinated in a distorted square-planar environment by two N atoms of the chelating 2-[(thiophen-2-ylmethyl)iminomethyl] pyridine ligand and two chloride anions. The thiophene ring is rotationally disordered over two orientations in a 1: 1 ratio. The crystal packing exhibits weak intermolecular C-H center dot center dot center dot Cl and C-H center dot center dot center dot S hydrogen bonds.
引用
收藏
页码:M1392 / U877
页数:9
相关论文
共 50 条
  • [31] The crystal structure of dichlorido-(2-((4-phenyl-2H-1,2,3-triazol-2-yl)methyl)pyridine-κ2N,N′)palladium(II), C14H12Cl2N4Pd
    Si, Xiang
    Yan, Qiong
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2022, 237 (02): : 205 - 206
  • [32] Dichlorido{N-[2-(diphenylphosphanyl)benzylidene]isopropylamine-κ2N,P}palladium(II) dimethyl sulfoxide monosolvate
    Chiririwa, Haleden
    Meijboom, Reinout
    Omondi, Bernard
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : M608 - U964
  • [33] Synthesis and Crystal Structure of Dichlorido{2-[(4-Methoxyphenyl)Iminomethyl]pyridine-k2N,N'}zinc
    M. Khalaj
    Crystallography Reports, 2020, 65 : 1121 - 1123
  • [34] Bis(dicyanamido-κN1)bis[2-(2-hydroxyethyl)pyridine-κ2N,O]nickel(II)
    Kong, Ling-Qian
    Ju, Xiu-Ping
    Li, Da-Cheng
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2009, 65 : M1518 - U253
  • [35] Synthesis and Crystal Structure of Dichlorido{2-[(4-Methoxyphenyl)Iminomethyl]pyridine-k2N,N′}zinc
    Khalaj, M.
    CRYSTALLOGRAPHY REPORTS, 2020, 65 (07) : 1121 - 1123
  • [36] Di-μ-chlorido-bis{chlorido[2-(2-furyl-methyliminomethyl)pyridine-κ2N,N′]nickel(II)}
    Xia, Dong-Sheng
    Chen, Wu
    Tang, Xin-Long
    Zeng, Qing-Fu
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2008, 64 : M836 - U977
  • [37] (η6-Benzene){2-[2-(tert-butylsulfanyl)phenyl]pyridine-κ2N,S}chloridoruthenium(II) hexafluoridophosphate
    Hirotsu, Masakazu
    Yogi, Akira
    Kinoshita, Isamu
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : M63 - +
  • [38] 2-(Thiophen-2-yl)-1-(thiophen-2-ylmethyl)-1H-benzimidazole
    Geiger, David K.
    Geiger, H. Cristina
    Williams, Leo
    Noll, Bruce C.
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2012, 68 : O420 - U785
  • [39] Dichloridobis{2-[(triphenylmethyl)amino]pyridine-κN}cadmium(II)
    Zhang, Guang-Ning
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2008, 64 : M357 - U755
  • [40] Dichloridobis{2-[(triphenylmethyl)-amino] pyridine-κN}zinc(II)
    Zhang, Guang-Ning
    Fang, Yong
    Huang, Cui-Ying
    You, Wan-Sheng
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2007, 63 : M2247 - U1973