Mechanism for the Formation of Elemental Sulfur from Modified Stretford Process

被引：1

作者：

Dong, Yue ^{[1
,2
,3
]}

Ling, KaiCheng ^{[2
]}

Zhang, WeiShuai ^{[2
]}

Luo, HuaFeng ^{[2
]}

机构：

[1] Taiyuan Univ Technol, Coll Environm Sci & Engn, Taiyuan 030024, ShanXi, Peoples R China

[2] Taiyuan Univ Technol, Coll Chem & Chem Engn, Taiyuan 030024, ShanXi, Peoples R China

[3] Taiyuan Heavy Machinery Grp Co Ltd, Coal Chem Equipment Subco, Taiyuan 030024, ShanXi, Peoples R China

来源：

FUNDAMENTAL OF CHEMICAL ENGINEERING, PTS 1-3 | 2011年 / 233-235卷

关键词：

Polysulfide ion; Elemental sulfur; Free radical mechanism; CV; Desulfurization process; SULFIDE;

D O I：

10.4028/www.scientific.net/AMR.233-235.892

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

In this paper, the mechanism for the formation of elemental sulfur from the modified Stretford process was investigated using cyclic voltammetry (CV). The results showed that hydrosulfide (HS-) is first oxidized to produce polysulfide ion (S-x(2-)) which is reactive intermediate product and will further transform to form elemental sulfur S-8. Additionally, a free radical reaction mechanism which describes the formation of elemental sulfur S-8 was proposed.

引用

页码：892 / +

页数：2

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