Hydrogen sorption properties of a MgH2-10 wt.% graphite mixture

被引:33
作者
Castro, F. J. [1 ,2 ]
Fuster, V. [1 ,2 ]
Urretavizcaya, G. [1 ,2 ]
机构
[1] Consejo Nacl Invest Cient & Tecn, CNEA, Ctr Atom Bariloche, San Carlos De Bariloche, Rio Negro, Argentina
[2] CNEA, UNCuyo, Inst Balseiro, San Carlos De Bariloche, Rio Negro, Argentina
关键词
Hydrogen storage; Hydrides; Sorption kinetics; Magnesium; Mechanical milling; MAGNESIUM HYDRIDE; STORAGE MATERIALS; DESORPTION; MG; DECOMPOSITION; KINETICS; COMPOSITES; CARBON; TEMPERATURE; ABSORPTION;
D O I
10.1016/j.jallcom.2011.01.069
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We present an analysis of the hydrogen absorption and desorption properties of a MgH2-10 wt.% graphite mixture prepared by reactive mechanical milling. The analysis is based on isothermal hydriding and dehydriding kinetic measurements and calorimetry experiments. The studied samples contained different hydrogen contents. From the characteristics of the sorption curves several features of the hydriding and dehydriding processes are identified. Additionally, the role of graphite in hydrogen sorption is analyzed. (C) 2011 Elsevier B.V. All rights reserved.
引用
收藏
页码:S595 / S598
页数:4
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