Photochromic behavior of retinal analogs

被引：5

作者：

Belikov, Nikolay ^{[1
]}

Lukin, Alexey ^{[1
]}

Laptev, Alexey ^{[1
]}

Shvets, Vitaly ^{[1
]}

Barachevsky, Valery ^{[2
]}

Strokach, Yury ^{[2
]}

Valova, Tat'yana ^{[2
]}

Krayushkin, Mikhail ^{[3
]}

Demina, Olga ^{[4
]}

Varfolomeev, S. Ergey ^{[4
]}

Khodonov, Andrey ^{[1
,4
]}

机构：

[1] MV Lomonosov State Acad Fine Chem Technol, Moscow 117571, Russia

[2] Photochem Ctr RAS, Moscow 119421, Russia

[3] ND Zelinsky Inst Organ Chem RAS, Moscow 119991, Russia

[4] NM Emanuel Inst Biochem Phys RAS, Moscow 119334, Russia

来源：

JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY | 2008年 / 196卷 / 2-3期

基金：

俄罗斯基础研究基金会;

关键词：

photochromism; diarylethenes; retinal analogs; retinoids;

D O I：

10.1016/j.jphotochem.2007.11.015

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

New dihetarylethenic retinal analogs were synthesized, and their photochromic behavior was studied. The relationship between the compound structures and their spectral and kinetic parameters was determined due to the comparative spectral-kinetic studies of synthesized dihetarylethenes. It was shown, that all synthesized compounds possess expressed photochromic properties and the thermal irreversibility. The best kinetic characteristics for the photocyclization process as well as a low photodegradation were measured for short-chain nitrile. (C) 2008 Elsevier B.V. All rights reserved.

引用

页码：262 / 267

页数：6

共 18 条

[1]

Balzani V., 2003, Molecular Devices and Machines, a Journey into the Nanoworld

[2] Photochromic organic compounds with polyfunctional properties [J].

Barachevsky, VA .

LASER SPECTROSCOPY AND OPTICAL DIAGNOSTICS: NOVEL TRENDS AND APPLICATIONS IN LASER CHEMISTRY, BIOPHYSICS, AND BIOMEDICINE - ICONO'98, 1999, 3732 :239-245

[3] Photochromism of thienyl-containing dihetarylethenes with five-membered cyclic bridges [J].

Barachevsky, VA ;

Strokach, YP ;

Krayushkin, MM .

MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 2005, 430 :181-186

[4] Polyfunctional photochromism of spirocompounds [J].

Barachevsky, VA .

MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 2000, 344 :277-282

[5]

Bens AT, 1998, EUR J ORG CHEM, V1998, P2333

[6]

Crano J. C., 1999, ORGANIC PHOTOCHROMIC, V2

[7]

Crano JC, 1999, T APPL CHEM, V1, P1

[8]

DRACHEV A L, 1987, Biokhimiya, V52, P1559

[9] LIGHT-TRIGGERED MOLECULAR DEVICES - PHOTOCHEMICAL SWITCHING OF OPTICAL AND ELECTROCHEMICAL PROPERTIES IN MOLECULAR WIRE TYPE DIARYLETHENE SPECIES [J].

GILAT, SL ;

KAWAI, SH ;

LEHN, JM .

CHEMISTRY-A EUROPEAN JOURNAL, 1995, 1 (05) :275-284

[10] THERMALLY IRREVERSIBLE PHOTOCHROMIC SYSTEMS - REVERSIBLE PHOTOCYCLIZATION OF DIARYLETHENE DERIVATIVES [J].

IRIE, M ;

MOHRI, M .

JOURNAL OF ORGANIC CHEMISTRY, 1988, 53 (04) :803-808

← 1 2 →