New synthetic strategies to prepare metal-organic frameworks

被引:275
作者
Li, Peng [1 ,2 ]
Cheng, Fang-Fang [3 ]
Xiong, Wei-Wei [1 ,2 ]
Zhang, Qichun [4 ]
机构
[1] Nanjing Tech Univ NanjingTech, Key Lab Flexible Elect KLOFE, 30 South Puzhu Rd, Nanjing 211816, Jiangsu, Peoples R China
[2] Nanjing Tech Univ NanjingTech, IAM, Jiangsu Natl Synerget Innovat Ctr Adv Mat SICAM, 30 South Puzhu Rd, Nanjing 211816, Jiangsu, Peoples R China
[3] Nanjing Univ Chinese Med, Sch Pharm, Nanjing 210023, Jiangsu, Peoples R China
[4] Nanyang Technol Univ, Sch Mat Sci & Engn, Singapore 639798, Singapore
基金
中国国家自然科学基金;
关键词
SURFACTANT-THERMAL METHOD; DEEP-EUTECTIC SOLVENTS; SLOW MAGNETIZATION RELAXATION; ROOM-TEMPERATURE SYNTHESIS; IONOTHERMAL SYNTHESIS; MECHANOCHEMICAL SYNTHESIS; COORDINATION POLYMERS; IONIC LIQUIDS; UROTHERMAL SYNTHESIS; CRYSTAL-STRUCTURES;
D O I
10.1039/c8qi00543e
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Metal-organic frameworks (MOFs) have attracted extensive research interest due to their rich structure chemistry and many potential industrial applications in the areas of gas separation and storage, catalysis, drug delivery, chemical sensors, magnetism, and others. The synthesis of MOF materials by convenient and environmentally friendly methods is highly desirable for the advancement of MOF chemistry. This critical review summarizes the recent developments in the application of new synthetic strategies for preparing MOFs, including the ionothermal method, deep eutectic solvent usage, surfactant-thermal process, and mechanochemistry. The roles of different solvents in the reaction systems are discussed.
引用
收藏
页码:2693 / 2708
页数:16
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