Design of Potassium-Selective Mixed Ion/Electron Conducting Polymers

被引：19

作者：

Villarroel Marquez, Ariana ^{[1
,2
]}

Salinas, Gerardo ^{[3
]}

Abarkan, Myriam ^{[2
]}

Idir, Mael ^{[1
]}

Brochon, Cyril ^{[1
]}

Hadziioannou, Georges ^{[1
]}

Raoux, Matthieu ^{[2
]}

Kuhn, Alexander ^{[3
]}

Lang, Jochen ^{[2
]}

Cloutet, Eric ^{[1
]}

机构：

[1] Univ Bordeaux, CNRS, Bordeaux INP, LCPO,UMR 5629, F-33615 Pessac, France

[2] Univ Bordeaux, CNRS, Bordeaux INP, CBMN,UMR 5248, F-33600 Bordeaux, France

[3] Univ Bordeaux, CNRS, Bordeaux INP, ISM,UMR 5255, F-33607 Bordeaux, France

来源：

MACROMOLECULAR RAPID COMMUNICATIONS | 2020年 / 41卷 / 12期

关键词：

conducting polymers; coulovoltammetry; crown ethers; ion sensing; PEDOT; ELECTROCHEMICAL MOLECULAR MACHINES; COOPERATIVE ACTUATION; CHEMICAL SENSORS; PEDOT-PSS; ELECTRODES; POLYELECTROLYTE; SENSES; FILMS;

D O I：

10.1002/marc.202000134

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

An approach providing cation-selective poly-(3,4-ethylenedioxythiophene)(PEDOT):polyelectrolyte-mixed conductors is presented in this communication based on the structural modification of this ambivalent (ionic and electronic conductive) polymer complex. First, an 18-crown-6 moiety is integrated into the styrene sulfonate monomer structure as a specific metal cation scavenger particularly targeting K+ versus Na+ detection. This newly functionalized monomer is characterized by H-1 NMR titration to evaluate the ion selectivity. Aqueous PEDOT dispersion inks containing the polymeric ion-selective moieties are designed and their electrical and electrochemical properties analyzed. These biocompatible inks are the first proof-of-concept step towards ion selectivity in view of their interfacing with biological cells and microorgans of interest in the field of biosensors and physiology.

引用

页数：7

共 32 条

[1] EDOT-Functionalized Calix[4]pyrrole for the Electrochemical Sensing of Fluoride in Water
Aydogan, Abdullah
Koca, Atif
Sener, M. Kasim
Sessler, Jonathan L.
[J]. ORGANIC LETTERS, 2014, 16 (14) : 3764 - 3767
[2] Ion Electron-Coupled Functionality in Materials and Devices Based on Conjugated Polymers
Berggren, Magnus
Crispin, Xavier
Fabiano, Simone
Jonsson, Magnus P.
Simon, Daniel T.
Stavrinidou, Eleni
Tybrandt, Klas
Zozoulenko, Igor
[J]. ADVANCED MATERIALS, 2019, 31 (22)
[3] Recent advances in polyaniline research: Polymerization mechanisms, structural aspects, properties and applications
Ciric-Marjanovic, Gordana
[J]. SYNTHETIC METALS, 2013, 177 : 1 - 47
[4] Groenendaal BL, 2000, ADV MATER, V12, P481, DOI 10.1002/(SICI)1521-4095(200004)12:7<481::AID-ADMA481>3.0.CO
[5] 2-C
[6] An Alternative Anionic Polyelectrolyte for Aqueous PEDOT Dispersions: Toward Printable Transparent Electrodes
Hofmann, Anna I.
Smaal, Wiljan T. T.
Mumtaz, Muhammad
Katsigiannopoulos, Dimitrios
Brochon, Cyril
Schuetze, Falk
Hild, Olaf R.
Cloutet, Eric
Hadziioannou, Georges
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2015, 54 (29) : 8506 - 8510
[7] Materials for Transparent Electrodes: From Metal Oxides to Organic Alternatives
Hofmann, Anna Isabel
Cloutet, Eric
Hadziioannou, Georges
[J]. ADVANCED ELECTRONIC MATERIALS, 2018, 4 (10):
[8] Conducting Polymers in the Fields of Energy, Environmental Remediation, and Chemical-Chiral Sensors
Ibanez, Jorge G.
Rincon, Marina. E.
Gutierrez-Granados, Silvia
Chahma, M'hamed
Jaramillo-Quintero, Oscar A.
Frontana-Uribe, Bernardo A.
[J]. CHEMICAL REVIEWS, 2018, 118 (09) : 4731 - 4816
[9] Benchmarking organic mixed conductors for transistors
Inal, Sahika
Malliaras, George G.
Rivnay, Jonathan
[J]. NATURE COMMUNICATIONS, 2017, 8
[10] Investigation of poly(3,4-ethylenedioxythiophene) deposition method influence on properties of ion-selective electrodes based on bis(benzo15-crown-5) derivatives
Jeszke, Maciej
Trzcinski, Konrad
Karczewski, Jakub
Luboch, Elzbieta
[J]. ELECTROCHIMICA ACTA, 2017, 246 : 424 - 432

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