Direct Carbonization of Al-Based Porous Coordination Polymer for Synthesis of Nanoporous Carbon

被引：610

作者：

Hu, Ming ^{[1
]}

Reboul, Julien ^{[2
,3
]}

Furukawa, Shuhei ^{[2
,3
]}

Torad, Nagy L. ^{[1
,4
]}

Ji, Qingmin ^{[1
]}

Srinivasu, Pavuluri ^{[1
]}

Ariga, Katsuhiko ^{[1
,5
]}

Kitagawa, Susumu ^{[2
,3
]}

Yamauchi, Yusuke ^{[1
,4
]}

机构：

[1] Natl Inst Mat Sci, Res Ctr Mat Nanoarchitecton MANA, Tsukuba, Ibaraki 3050044, Japan

[2] Japan Sci & Technol Agcy JST, ERATO Kitagawa Integrated Pores Project, Kyoto 6008815, Japan

[3] Kyoto Univ, Inst Integrated Cell Mat Sci iCeMS, Sakyo Ku, Kyoto 6068501, Japan

[4] Waseda Univ, Fac Sci & Engn, Shinjuku Ku, Tokyo 1698555, Japan

[5] Japan Sci & Technol Agcy JST, Kawaguchi, Saitama 3320012, Japan

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2012年 / 134卷 / 06期

关键词：

METAL-ORGANIC FRAMEWORKS; HIGH-SURFACE-AREA; MESOPOROUS CARBON; MICROPOROUS CARBON; ADSORPTION; STORAGE; RECOGNITION; PERFORMANCE; SEPARATION; ACETYLENE;

D O I：

10.1021/ja208940u

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Nanoporous carbon (NPC) is prepared by direct carbonization of Al-based porous coordination polymers (Al-PCP). By applying the appropriate carbonization temperature, both high surface area and large pore volume are realized for the first time. Our NPC shows much higher porosity than other carbon materials (such as activated carbons and mesoporous carbons). This new type of carbon material exhibits superior sensing capabilities toward toxic aromatic substances.

引用

页码：2864 / 2867

页数：4

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