Direct Carbonization of Al-Based Porous Coordination Polymer for Synthesis of Nanoporous Carbon

被引:608
作者
Hu, Ming [1 ]
Reboul, Julien [2 ,3 ]
Furukawa, Shuhei [2 ,3 ]
Torad, Nagy L. [1 ,4 ]
Ji, Qingmin [1 ]
Srinivasu, Pavuluri [1 ]
Ariga, Katsuhiko [1 ,5 ]
Kitagawa, Susumu [2 ,3 ]
Yamauchi, Yusuke [1 ,4 ]
机构
[1] Natl Inst Mat Sci, Res Ctr Mat Nanoarchitecton MANA, Tsukuba, Ibaraki 3050044, Japan
[2] Japan Sci & Technol Agcy JST, ERATO Kitagawa Integrated Pores Project, Kyoto 6008815, Japan
[3] Kyoto Univ, Inst Integrated Cell Mat Sci iCeMS, Sakyo Ku, Kyoto 6068501, Japan
[4] Waseda Univ, Fac Sci & Engn, Shinjuku Ku, Tokyo 1698555, Japan
[5] Japan Sci & Technol Agcy JST, Kawaguchi, Saitama 3320012, Japan
关键词
METAL-ORGANIC FRAMEWORKS; HIGH-SURFACE-AREA; MESOPOROUS CARBON; MICROPOROUS CARBON; ADSORPTION; STORAGE; RECOGNITION; PERFORMANCE; SEPARATION; ACETYLENE;
D O I
10.1021/ja208940u
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Nanoporous carbon (NPC) is prepared by direct carbonization of Al-based porous coordination polymers (Al-PCP). By applying the appropriate carbonization temperature, both high surface area and large pore volume are realized for the first time. Our NPC shows much higher porosity than other carbon materials (such as activated carbons and mesoporous carbons). This new type of carbon material exhibits superior sensing capabilities toward toxic aromatic substances.
引用
收藏
页码:2864 / 2867
页数:4
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