Polypyrrole thin film fiber optic chemical sensor for detection of VOCs

被引:50
|
作者
Qin, Hongyi [1 ,3 ,4 ]
Kukarni, Atul [1 ]
Zhang, Hang [2 ]
Kim, Hojoong [2 ]
Jiang, Dong [3 ,4 ]
Kim, Taesung [1 ,2 ]
机构
[1] Sungkyunkwan Univ, Sch Mech Engn, Suwon 440746, South Korea
[2] Sungkyunkwan Univ, SAINT, Suwon 440746, South Korea
[3] Jilin Univ, Minist Educ, Engn Res Ctr High Performance Plast, Changchun 130012, Peoples R China
[4] Jilin Univ, Coll Chem, Changchun 130012, Peoples R China
基金
新加坡国家研究基金会;
关键词
Polypyrrole; Thin film; Polymer optical fiber; Reflectance; Volatile organic compounds; AMMONIA GAS; CONDUCTIVITY; POLARON;
D O I
10.1016/j.snb.2011.06.009
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
A fiber optic reflectance sensor (FORS) using Polypyrrole (PPy) conducting polymer to detect volatile organic compounds (VOCs) is demonstrated. The conventional interfacial polymerization method is used to synthesize a sensitive polypyrrole membrane, which shows relatively low roughness and high reflectivity. In general the changes in electrical properties of conductive polymers are explored in sensing applications, however their optical properties have been less explored. In the present study, we evaluate the optical properties of PPy and transfer on the end face of polymer optical fiber (POF) for the detection of VOCs. The change in the reflected optical signal from PPy upon interaction with the VOCs is systematically evaluated. The fabricated PPy FORS shows the excellent sensitivity to the VOCs under test with the detection limit up to 1 ppm. (C) 2011 Elsevier B.V. All rights reserved.
引用
收藏
页码:223 / 228
页数:6
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