Alkyl 3-Nitroacrylates in Reactions with Substituted Hydrazines

被引：0

作者：

Pelipko, V. V. ^{[1
]}

Adyukov, I. S. ^{[1
]}

Baichurin, R., I ^{[1
]}

Makarenko, S., V ^{[1
]}

机构：

[1] Herzen State Pedag Univ Russia, St Petersburg 191186, Russia

来源：

RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2022年 / 92卷 / 02期

关键词：

nitroacrylates; substituted hydrazine; hydrazides; nucleophilic addition; aza-Michael adduct; hydrazone; STEREOSELECTIVE-SYNTHESIS; BETA-NITROACRYLATES; CONSTRUCTION; ALDEHYDES; VERSATILE; CARBON;

D O I：

10.1134/S1070363222020013

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reactions of alkyl 3-nitroacrylates with representatives of aryl(hetaryl) carboxylic acid hydrazides and substituted phenylhydrazines were studied. It was shown that the reactions proceed along the path of the formation of aza-Michael adducts. Elimination of nitrous acid by the action of a base from aza-adducts leads to the formation of N '-substituted E-hydrazones of alkyl pyruvates.

引用

页码：141 / 146

页数：6

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