Frustrated Lewis Pair Chemistry: Development and Perspectives

被引：1376
作者：
Stephan, Douglas W. [1 ]
Erker, Gerhard [2 ]
机构：
[1] Univ Toronto, Dept Chem, Toronto, ON M5S 3H6, Canada
[2] Univ Munster, Organ Chem Inst, D-48149 Munster, Germany
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2015年 / 54卷 / 22期
基金：
欧洲研究理事会; 加拿大自然科学与工程研究理事会;
关键词：
cooperative reactions; frustrated Lewis pairs; metal-free hydrogenation; small-molecule activation; FREE CATALYTIC-HYDROGENATION; HETEROLYTIC DIHYDROGEN ACTIVATION; METAL-FREE HYDROGENATION; N-HETEROCYCLIC CARBENE; H BOND ACTIVATION; ASYMMETRIC TRANSFER HYDROGENATION; OLEFIN POLYMERIZATION; ADDUCT FORMATION; CARBON-DIOXIDE; COORDINATION-COMPOUNDS;
D O I：
10.1002/anie.201409800
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Frustrated Lewis pairs (FLPs) are combinations of Lewis acids and Lewis bases in solution that are deterred from strong adduct formation by steric and/or electronic factors. This opens pathways to novel cooperative reactions with added substrates. Small-molecule binding and activation by FLPs has led to the discovery of a variety of new reactions through unprecedented pathways. Hydrogen activation and subsequent manipulation in metal-free catalytic hydrogenations is a frequently observed feature of many FLPs. The current state of this young but rapidly expanding field is outlined in this Review and the future directions for its broadening sphere of impact are considered.
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页码：6400 / 6441
页数：42
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