Shape Matters: Plasmonic Nanoparticle Shape Enhances Interaction with Dielectric Substrate

被引:115
作者
Albella, Pablo [2 ]
Garcia-Cueto, Borja [2 ]
Gonzalez, Francisco [2 ]
Moreno, Fernando [2 ]
Wu, Pae C. [3 ]
Kim, Tong-Ho [3 ]
Brown, April [3 ]
Yang, Yang [4 ]
Everitt, Henry O. [3 ,4 ,5 ]
Videen, Gorden [1 ]
机构
[1] USA, Res Lab, RMRD CIE S, Adelphi, MD 20783 USA
[2] Univ Cantabria, Dept Fis Aplicada, Grp Opt, E-39005 Santander, Spain
[3] Duke Univ, Dept Elect & Comp Engn, Durham, NC 27708 USA
[4] Duke Univ, Dept Phys, Durham, NC 27708 USA
[5] USA, Aviat & Missile RD & E Ctr, RDMR WS, Redstone Arsenal, AL 35898 USA
关键词
UV plasmonics; nanoparticles; gallium; shape effects; substrate effects; nanoantenna; DISCRETE-DIPOLE APPROXIMATION; OPTICAL-PROPERTIES; METAL NANOPARTICLES; RESONANCE SPECTROSCOPY; SCATTERING; PARTICLE;
D O I
10.1021/nl201783v
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Numerical analyses of the ultraviolet and visible plasmonic spectra measured from hemispherical gallium nanostructures on dielectric substrates reveal that resonance frequencies are quite sensitive to illumination angle and polarization in a way that depends on nanostructure size, shape, and substrate. Large, polarization-dependent splittings arise from the broken symmetry of hemispherical gallium nanoparticles on sapphire substrates, inducing strong interactions with the substrate that depend sensitively on the angle of illumination and the nanoparticle diameter.
引用
收藏
页码:3531 / 3537
页数:7
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