Oxidative Addition of Disulfides, Alkyl Sulfides, and Diphosphides to an Aluminum(I) Center

被引：31
作者：
Chu, Terry [1 ]
Boyko, Yaroslav [1 ]
Korobkov, Ilia [2 ]
Kuzmina, Lyudmila G. [3 ]
Howard, Judith A. K. [4 ]
Nikonov, Georgii I. [1 ]
机构：
[1] Brock Univ, Dept Chem, 1812 Sir Isaac Brock Way, St Catharines, ON L2S 3A1, Canada
[2] Univ Ottawa, Fac Sci, Xray Core Facil, 150 Louis Pasteur, Ottawa, ON K1N 6N5, Canada
[3] NS Kurnakov Gen & Inorgan Chem Inst, 31 Leninskii Prospekt, Moscow 119991, Russia
[4] Univ Durham, Dept Chem, South Rd, Durham DH1 3LE, England
来源：
INORGANIC CHEMISTRY | 2016年 / 55卷 / 17期
关键词：
FRUSTRATED LEWIS PAIRS; FREE HYDROGEN ACTIVATION; MAIN-GROUP COMPOUNDS; P BOND ACTIVATION; GROUP ELEMENTS; CARBON-SULFUR; S-S; COMPLEXES; COORDINATION; COMPOUND;
D O I：
10.1021/acs.inorgchem.6b01668
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The aluminum(I) compound NacNacAl (1) reacts with diphenyl disulfide and diethyl sulfide to form the respective four-coordinate bis(phenyl sulfide) complex NacNacAl(SPh)(2) (2) and alkyl thiolate aluminum complex NacNacAlEt(SEt) (3). As well, reaction of 1 with tetraphenyl diphosphine furnishes the bis(diphenyl phosphido) complex NacNacAl(PPh2)(2) (4). Production of 3 and 4 are the first examples of C(sp(3))-S and R2P-PR2 activation by a main-group element complex. All three complexes were characterized by multinuclear NMR spectroscopy and X-ray crystal structure analysis. Furthermore, a variable-temperature NMR spectroscopic study was undertaken on 4 to study its dynamic behavior in solution.
引用
收藏
页码：9099 / 9104
页数：6
相关论文
共 70 条
  • [1] [Anonymous], 2001, SADABS
  • [2] [Anonymous], 2012, APEX SOFTW SUIT V 20
  • [3] N-Heterocyclic Carbene Analogues with Low-Valent Group 13 and Group 14 Elements: Syntheses, Structures, and Reactivities of a New Generation of Multitalented Ligands
    Asay, Matthew
    Jones, Cameron
    Driess, Matthias
    [J]. CHEMICAL REVIEWS, 2011, 111 (02) : 354 - 396
  • [4] Bai G, 2006, DALTON T, P1141, DOI 10.1039/b513892b
  • [5] CHARACTERIZATION AND INTERCONVERSION OF METAL-PHOSPHORUS SINGLE AND DOUBLE-BONDS - BIS(CYCLOPENTADIENYL)ZIRCONIUM AND HAFNIUM BIS(DIORGANOPHOSPHIDE) COMPLEXES
    BAKER, RT
    WHITNEY, JF
    WREFORD, SS
    [J]. ORGANOMETALLICS, 1983, 2 (08) : 1049 - 1051
  • [6] Oxidative Addition of Diethylchalcogenanes to Lappert's Germylene and Stannylene
    Bendt, Georg
    Lapsien, Silvia
    Steiniger, Phillip
    Blaeser, Dieter
    Woelper, Christoph
    Schulz, Stephan
    [J]. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2015, 641 (05): : 797 - 802
  • [7] *BRUK AXS, 1997, SHELXTL PLUS REL 5 1
  • [8] First-row transition metal catalyzed reduction of carbonyl functionalities: a mechanistic perspective
    Chakraborty, Sumit
    Guan, Hairong
    [J]. DALTON TRANSACTIONS, 2010, 39 (32) : 7427 - 7436
  • [9] Transition Metal-like Oxidative Addition of C-F and C-O Bonds to an Aluminum(I) Center
    Chu, Terry
    Boyko, Yaroslav
    Korobkov, Ilia
    Nikonov, Georgii I.
    [J]. ORGANOMETALLICS, 2015, 34 (22) : 5363 - 5365
  • [10] Oxidative Addition of σ Bonds to an Al(I) Center
    Chu, Terry
    Korobkov, Ilia
    Nikonov, Georgii I.
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2014, 136 (25) : 9195 - 9202
1234567