A Novel Family of Polyiodo-Bromoantimonate(III) Complexes: Cation-Driven Self-Assembly of Photoconductive Metal-Polyhalide Frameworks

被引：68

作者：

Adonin, Sergey A. ^{[1
,2
]}

Udalova, Liubov I. ^{[1
,2
]}

Abramov, Pavel A. ^{[1
,2
]}

Novikov, Alexander S. ^{[3
]}

Yushina, Irina V. ^{[1
]}

Korolkov, Ilya V. ^{[1
,2
]}

Semitut, Evgeniy Y. ^{[1
]}

Derzhavskaya, Tatiyana A. ^{[4
]}

Stevenson, Keith J. ^{[5
]}

Troshin, Pavel A. ^{[4
,5
]}

Sokolov, Maxim N. ^{[1
,2
]}

Fedin, Vladimir P. ^{[1
,2
]}

机构：

[1] Nikolaev Inst Inorgan Chem SB RAS, Lavrentieva St 3, Novosibirsk 630090, Russia

[2] Novosibirsk State Univ, Pirogova St 2, Novosibirsk 630090, Russia

[3] St Petersburg State Univ, Inst Chem, Univ Skaya Nab 7-9, St Petersburg 199034, Russia

[4] RAS, Inst Problems Chem Phys, Semenov Ave 1, Chernogolovka 142432, Russia

[5] Skolkovo Inst Sci & Technol, Nobelya St 3, Moscow 121205, Russia

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2018年 / 24卷 / 55期

基金：

俄罗斯基础研究基金会;

关键词：

antimony; DFT calculations; halometalate; photoconductivity; polyhalide; CRYSTAL-STRUCTURE; POLYIODIDE NETWORKS; HALOGEN; NONABROMOANTIMONATE(V); CHEMISTRY; COMPOUND; BROMINE; IODIDES; ANIONS; I-2;

D O I：

10.1002/chem.201802100

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In the presence of different cations, reactions of [SbBr6](3-) and I-2 result in a new family of diverse supramolecular 1D polyiodide-bromoantimonate networks. The coordination number of Sb, as well as geometry of assembling {I-x}(n-) polyhalide units, can vary, resulting in unprecedented structural types. The nature of I...Br interactions was studied by DFT calculations; estimated energy values are 1.6-6.9 kcal mol(-1). Some of the compounds showed strong photoconductivity in thin films, suggesting multiple feasible applications in optoelectronics and solar energy conversion.

引用

页码：14707 / 14711

页数：5

共 56 条

[1] Polyhalide-bonded metal complexes: Structural diversity in an eclectic class of compounds [J].

Adonin, Sergey A. ;

Sokolov, Maxim N. ;

Fedin, Vladimir P. .

COORDINATION CHEMISTRY REVIEWS, 2018, 367 :1-17

[2] Bromo- and Polybromoantimonates(V): Structural and Theoretical Studies of Hybrid Halogen-Rich Halometalate Frameworks [J].

Adonin, Sergey A. ;

Bondarenko, Mikhail A. ;

Abramov, Pavel A. ;

Novikov, Alexander S. ;

Plyusnin, Pavel E. ;

Sokolov, Maxim N. ;

Fedin, Vladimir P. .

CHEMISTRY-A EUROPEAN JOURNAL, 2018, 24 (40) :10165-10170

[3] Bi(III) polybromides: a new chapter in coordination chemistry of bismuth [J].

Adonin, Sergey A. ;

Gorokh, Igor D. ;

Samsonenko, Denis G. ;

Sokolov, Maxim N. ;

Fedin, Vladimir P. .

CHEMICAL COMMUNICATIONS, 2016, 52 (28) :5061-5063

[4]

[Anonymous], 2016, ANGEW CHEM

[5] A QUANTUM-THEORY OF MOLECULAR-STRUCTURE AND ITS APPLICATIONS [J].

BADER, RFW .

CHEMICAL REVIEWS, 1991, 91 (05) :893-928

[6] Polymeric anionic networks using dibromine as a crosslinker; the preparation and crystal structure of [(C4H9)4N]2[Pt2Br10]•(Br2)7 and [(C4H9)4N]2[PtBr4Cl2]•(Br2)6 [J].

Berkei, M ;

Bickley, JF ;

Heaton, BT ;

Steiner, A .

CHEMICAL COMMUNICATIONS, 2002, (18) :2180-2181

[7] Type structure, which is composed of organic diammonium, triiodide and hexaiodobismuthate, varies according to different structures of incorporated cations [J].

Bi, Wenhua ;

Louvain, Nicolas ;

Mercier, Nicolas ;

Luc, Jerome ;

Sahraoui, Bouchta .

CRYSTENGCOMM, 2007, 9 (04) :298-303

[8]

Bruckner R., 2015, Angew. Chem, V127, P15800

[9] A 2D Polychloride Network Held Together by Halogen-Halogen Interactions [J].

Brueckner, Robin ;

Haller, Heike ;

Steinhauer, Simon ;

Mueller, Carsten ;

Riedel, Sebastian .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2015, 54 (51) :15579-15583

[10] The Halogen Bond [J].

Cavallo, Gabriella ;

Metrangolo, Pierangelo ;

Milani, Roberto ;

Pilati, Tullio ;

Priimagi, Arri ;

Resnati, Giuseppe ;

Terraneo, Giancarlo .

CHEMICAL REVIEWS, 2016, 116 (04) :2478-2601

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