Protein powder derived nitrogen-doped carbon supported atomically dispersed iron sites for selective oxidation of ethylbenzene

被引：12
作者：
Cheng, Yujie [1 ]
Sun, Qingdi [1 ]
Huang, Liyun [1 ]
He, Qian [1 ]
Zhang, Hao [1 ]
Wang, Pengbo [2 ]
Zhang, Ying [3 ]
Shi, Shaolin [2 ]
Zhang, Xingcong [1 ]
Gan, Tao [1 ]
He, Xiaohui [1 ,3 ]
Ji, Hongbing [1 ,2 ,3 ,4 ]
机构：
[1] Sun Yat Sen Univ, Sch Chem, Fine Chem Ind Res Inst, Guangzhou 510275, Guangdong, Peoples R China
[2] Guangxi Univ, Sch Chem & Chem Engn, Nanning 530004, Peoples R China
[3] Sun Yat Sen Univ, Huizhou Res Inst, Huizhou 516216, Peoples R China
[4] Guangdong Univ Petrochem Technol, Sch Chem Engn, Maoming 525000, Peoples R China
来源：
DALTON TRANSACTIONS | 2021年 / 50卷 / 34期
基金：
中国国家自然科学基金;
关键词：
POROUS CARBON; EFFICIENT; CATALYSTS; COBALT; NANOCATALYST; SULFOXIDES; ALCOHOLS; NITRIDE; SOLVENT; GREEN;
D O I：
10.1039/d1dt02001c
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Atomically dispersed Fe species embedded in the nitrogen-containing carbon supports (Fe-1/NC) are successfully synthesized using a ball milling approach, with commercial protein powder as the nitrogen source. The catalyst exhibits outstanding performance in the oxidation of aromatic compounds containing saturated C-H bonds into corresponding ketones under ambient conditions, which is superior to those of a nanoparticle catalyst (Fe-n/NC) and a metal-free catalyst (NC).
引用
收藏
页码：11711 / 11715
页数：6
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