Mg-NHC complex on the surface of nanomagnesium oxide for catalytic application

被引：17

作者：

Shaikh, Melad ^{[1
]}

Sahu, Mahendra ^{[1
]}

Gavel, Pramod Kumar ^{[1
]}

Turpu, Goverdhan Reddy ^{[1
]}

Khilari, Santimoy ^{[2
]}

Pradhan, Debabrata ^{[2
]}

Ranganath, Kalluri V. S. ^{[1
]}

机构：

[1] Cent Univ, Sch Phys Sci, Bilaspur 495009, India

[2] Indian Inst Technol, Ctr Mat Sci, Kharagpur 721302, W Bengal, India

来源：

CATALYSIS COMMUNICATIONS | 2016年 / 84卷

关键词：

Nano-Mg; Mg-NHC; C-C bond formation; Dehydration; Heterogeneous; N-HETEROCYCLIC CARBENES; ASYMMETRIC ORGANOCATALYSIS; ZIRCONIUM-PHOSPHATE; HENRY REACTION; MAGNESIUM; FRUCTOSE; METALLOCENES; DEHYDRATION; ADDUCTS; ZINC;

D O I：

10.1016/j.catcom.2016.06.007

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We have developed a simple and eco-friendly protocol for the synthesis of Mg-NHC complexes. The Mg-NHC complex is prepared by reacting nano-MgO with imidazolium salts. Thus prepared Mg-NHC complex has been realized in two divergent reactions one in C-C bond formation and other in dehydration reaction. Further, the Mg-NHC catalyst has been characterized by SEM, TEM, XPS, Raman Spectroscopy and XRD analysis. (C) 2016 Elsevier B.V. All rights reserved.

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页码：89 / 92

页数：4

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