Hyper/highly-branched polymers by radical polymerisations

被引：84

作者：

England, Richard Mark ^{[1
]}

Rimmer, Stephen ^{[1
]}

机构：

[1] Univ Sheffield, Polymer & Biomat Chem Labs, Dept Chem, Sheffield S3 7HF, S Yorkshire, England

来源：

POLYMER CHEMISTRY | 2010年 / 1卷 / 10期

关键词：

FRAGMENTATION CHAIN TRANSFER; AMPHIPHILIC HYPERBRANCHED FLUOROPOLYMERS; CONDENSING VINYL POLYMERIZATION; RING-OPENING POLYMERIZATION; TRANSFER RAFT; POLY(METHYL METHACRYLATE)S; FACILE SYNTHESIS; POLY(BUTYL METHACRYLATE); DIBLOCK COPOLYMERS; BUTYL ACRYLATE;

D O I：

10.1039/c0py00154f

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Hyper branched and highly branched polymers (HB polymers) can be prepared by a variety of radical polymerisations. Here we describe the various techniques that can be used and include hybrid polymerisations that involve both radical and ring opening polymerisations. Adaptations of established techniques that use transfer to monomer are described. Then controlled radical polymerisations are outlined. Finally, some of emergent applications are reviewed with a special emphasis on applications in the life sciences.

引用

页码：1533 / 1544

页数：12

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