Amperometric Determination of Nicotine using a Composite of Palladium hexacyanoferrate incorporated Graphene oxide modified Electrode

被引：0

作者：

Yang, Cheng Yu ^{[1
]}

Chang, Min-Hui ^{[1
]}

Chen, Shen-Ming ^{[1
]}

Devadas, Balamurugan ^{[1
]}

机构：

[1] Natl Taipei Univ Technol, Dept Chem Engn & Biotechnol, Electroanal & Bioelectrochem Lab, 1,Sect 3,Chung Hsiao East Rd, Taipei 106, Taiwan

来源：

INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE | 2016年 / 11卷 / 04期

关键词：

Palladium hexacyanoferrate; graphene oxide; nicotine; amperometry; electrochemical method; GLASSY-CARBON ELECTRODE; ELECTROCHEMICAL DETECTION; VOLTAMMETRIC DETERMINATION; GRAPHITE ELECTRODE; TOBACCO PRODUCTS; SENSOR; NICKEL; NANOCOMPOSITE; NANOPARTICLES; ENHANCEMENT;

D O I：

暂无

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

Herein, we report a highly sensitive amperometric nicotine (NIC) sensor using composite of palladium hexacyanoferrate (PdHCF) with graphene oxide (GO) modified glassy carbon electrode (GCE). The PdHCF particles were deposited on GO modified GCE using an electrochemical method. The electrocatalytic measurements and surface morphology of the as prepared composite modified electrode were studied using cyclic voltammetry, amperometry, electrochemical impedance spectroscopy and scanning electron microscopy. The PdHCF incorporated GO composite modified electrode exhibits a prominent electrocatalytic activity towards the NIC than that of other modified electrodes. Furthermore, the presence of GO with PdHCF has greatly enhanced the surface coverage concentration and electron transfer rate constant when compared to only PdHCF and GO. The composite modified electrode shows the linear range from 8 to 240 mu M for NIC with the analytical sensitivity of 1.208 mu A mu M-1 cm(-2).

引用

页码：2650 / 2658

页数：9

共 45 条

[21] A Single-Step Extraction Method for the Determination of Nicotine and Cotinine in Jordanian Smokers' Blood and Urine Samples by RP-HPLC and GC-MS [J].

Maissadeh, Adnan M. ;

Gharaibeh, Ahmad A. ;

Omari, Khaled W. .

JOURNAL OF CHROMATOGRAPHIC SCIENCE, 2009, 47 (02) :170-177

[22] ELECTROCHEMICAL OXIDATION AND REDUCTION OF THIN-FILMS OF PRUSSIAN BLUE [J].

NEFF, VD .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1978, 125 (06) :886-887

[23]

Palanisamy S., 2015, RSC ADV, V5

[24] Quitlines and Nicotine Replacement for Smoking Cessation: Do We Need to Change Policy? [J].

Pierce, John P. ;

Cummins, Sharon E. ;

White, Martha M. ;

Humphrey, Aimee ;

Messer, Karen .

ANNUAL REVIEW OF PUBLIC HEALTH, VOL 33, 2012, 33 :341-+

[25] Electrochemical synthesis of dysprosium hexacyanoferrate micro stars incorporated multi walled carbon nanotubes and its electrocatalytic applications [J].

Rajkumar, Muniyandi ;

Devadas, Balamurugan ;

Chen, Shen-Ming .

ELECTROCHIMICA ACTA, 2013, 105 :439-446

[26] Electrochemical characteristics of dopamine oxidation at palladium hexacyanoferrate film, electroless plated on aluminum electrode [J].

Razmi, H ;

Azadbakht, A .

ELECTROCHIMICA ACTA, 2005, 50 (11) :2193-2201

[27] Electrochemical characterization of Prussian blue type nickel hexacyanoferrate redox mediator for potential application as charge relay in dye-sensitized solar cells [J].

Rutkowska, Iwona A. ;

Andrearczyk, Adam ;

Zoladek, Sylwia ;

Goral, Monika ;

Darowicki, Kazimierz ;

Kulesza, Pawel J. .

JOURNAL OF SOLID STATE ELECTROCHEMISTRY, 2011, 15 (11-12) :2545-2552

[28]

Sattarahmady N., 2013, SENSOR ACTUAT B-CHEM, V77, P1098

[29]

Sharma O., 2013, Int. J. ChemTech Res, V5, P1615

[30] Rapid and Chemically Selective Nicotine Quantification in Smokeless Tobacco Products using GC-MS [J].

Stanfill, Stephen B. ;

Jia, Lily T. ;

Ashley, David L. ;

Watson, Clifford H. .

JOURNAL OF CHROMATOGRAPHIC SCIENCE, 2009, 47 (10) :902-909

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