Neutral isonitrile adducts of alkali and alkaline earth metals

被引：30

作者：

Caro, CF ^{[1
]}

Hitchcock, PB ^{[1
]}

Lappert, MF ^{[1
]}

Layh, M ^{[1
]}

机构：

[1] Univ Sussex, Chem Lab, Brighton BN1 9QJ, E Sussex, England

来源：

CHEMICAL COMMUNICATIONS | 1998年 / 12期

关键词：

D O I：

10.1039/a708976g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Isonitriles are shown to form stable neutral adducts with some group 1 and 2 metal complexes; the synthesis and structures of [Li(N(R)C(Ph)NC (Ph)=CR2)(CNPh)](2), [LiNR2(CNPh)](2), [Mg(CHR2)(2)(CNC6H3Me2-2,6)(2)] and [Mg(CHR2)(mu-Br)(CNBut)](2) are described(R = SiMe3).

引用

页码：1297 / 1298

页数：2

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