Kinetics of base hydrolysis of low-spin iron(II)-diimine complexes in methanol-water mixtures

被引：0

作者：

Abu Gharib, EEA

Gosal, N

Burgess, J ^{[1
]}

机构：

[1] Univ Leicester, Dept Chem, Leicester LE1 7RH, Leics, England

[2] S Valley Univ, Fac Sci, Sohag 82524, Egypt

来源：

CROATICA CHEMICA ACTA | 2001年 / 74卷 / 03期

关键词：

low-spin iron(II)-diimine complexes; base hydrolysis; kinetics;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Rate constants are reported for base hydrolysis of several low-spin iron(II)-diimine complexes, mostly of polydentate ligands, in water and in aqueous methanol (up to 40% methanol). Rate constant trends from these and earlier studies of a variety of iron(II)-diimine complexes are compared and discussed in terms of ligand structure, ligand substituents, and solvation properties of the various complexes.

引用

页码：545 / 558

页数：14

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