Controlled grafting of cellulose fibres - an outlook beyond paper and cardboard

被引:115
作者
Malmstrom, Eva [1 ]
Carlmark, Anna [1 ]
机构
[1] KTH Royal Inst Technol, Sch Chem Sci & Engn, Dept Fibre & Polymer Technol, SE-10044 Stockholm, Sweden
基金
瑞典研究理事会;
关键词
TRANSFER RADICAL POLYMERIZATION; TRANSFER RAFT POLYMERIZATION; SURFACE MODIFICATION; BLOCK-COPOLYMER; RAMIE FIBER; ATRP; MEMBRANES; POLYSTYRENE; POLYMERS; FUNCTIONALIZATION;
D O I
10.1039/c1py00445j
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Cellulose is highly interesting from a materials science perspective, very much fuelled by its abundance, renewability and low cost. In this review, the heterogeneous grafting of cellulose fibres through controlled radical polymerization methods is highlighted. Techniques such as atom transfer radical polymerization (ATRP) and reversible addition fragmentation chain-transfer (RAFT) allow for fibres with tailorable properties and built-in functionality to be produced. Undoubtedly, cellulose is a material for the future and it is foreseen that in a few years, the use of cellulose will probably extend far beyond the traditional application areas, such as in paper and cardboard.
引用
收藏
页码:1702 / 1713
页数:12
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