Unraveling dissolved organic matter in drinking water through integrated ozonation/ceramic membrane and biological activated carbon process using FT-ICR MS

The performance of an integrated process comprising coagulation, ozonation, and catalytic ceramic membrane filtration (CMF) followed by treatment with biological active carbon (BAC) was evaluated in a pilot-scale (96 m(3)/d) experiment to understand the biostability and quality of the finished water. The fate of dissolved organic matter (DOM) at the molecular level was explored using Fourier-transform ion cyclotron resonance mass spectrometry (FT-ICR MS). Biostable finished water with an assimilable organic carbon (AOC) concentration of 30.2-45.4 mu g/L was obtained by the integrated process, and the high hydraulic retention time (HRT) (>= 45 min) of the BAC filter was necessary to provide biostable finished water. The coagulation/O-3/CMF unit efficiently transformed nitrogen-containing polyaromatic hydrocarbons (PAH) with aromaticity and large molecular weight (Mw) (500-1000 Da) into CHO-type highly unsaturated phenolic compounds (HuPh) with less aromaticity and medium Mw (300-500 Da), which were effectively removed by subsequent BAC filtering. The main reaction was oxygen addition, followed by deamination and dealkylation of the coagulation/O-3/CMF unit and decarboxylation of the BAC filter. Principal component analysis revealed that N-containing and large-Mw PAH are potential AOC precursors, and the chemical characteristics of CHO-type and medium-Mw HuPh make them AOC candidates (correlation coefficients > 0.96). This study provides insights into the management of drinking water biostability and its suitability for the practical application of the integrated coagulation/O-3/CMF-BAC process in drinking water treatment plants.