Ring-opening metathesis polymerization of functionalized low-strain monomers with ruthenium-based catalysts

被引：103
|
作者：
Hejl, A [1 ]
Scherman, OA [1 ]
Grubbs, RH [1 ]
机构：
[1] CALTECH, Div Chem & Chem Engn, Arnold & Mabel Beckman Labs Chem Synth, Pasadena, CA 91125 USA
来源：
MACROMOLECULES | 2005年 / 38卷 / 17期
关键词：
D O I：
10.1021/ma0501287
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
A detailed study of the ring-opening metathesis polymerization of low-strain monomers with ruthenium catalysts is reported. The effects of monomer concentration and catalyst dependence are described for unsubstituted cycloolefins. The ROMP of low-strain olefins with polar substituents is also examined with ruthenium olefin metathesis catalysts, and a predictive model for ROMP feasibility is proposed.
引用
收藏
页码：7214 / 7218
页数：5
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