Ring-opening metathesis polymerization of functionalized low-strain monomers with ruthenium-based catalysts

被引：105

作者：

Hejl, A ^{[1
]}

Scherman, OA ^{[1
]}

Grubbs, RH ^{[1
]}

机构：

[1] CALTECH, Div Chem & Chem Engn, Arnold & Mabel Beckman Labs Chem Synth, Pasadena, CA 91125 USA

来源：

MACROMOLECULES | 2005年 / 38卷 / 17期

关键词：

D O I：

10.1021/ma0501287

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

A detailed study of the ring-opening metathesis polymerization of low-strain monomers with ruthenium catalysts is reported. The effects of monomer concentration and catalyst dependence are described for unsubstituted cycloolefins. The ROMP of low-strain olefins with polar substituents is also examined with ruthenium olefin metathesis catalysts, and a predictive model for ROMP feasibility is proposed.

引用

页码：7214 / 7218

页数：5

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