Na2Ti3O7: Lowest Voltage Ever Reported Oxide Insertion Electrode for Sodium Ion Batteries

被引：733

作者：

Senguttuvan, Premkumar ^{[1
,2
]}

Rousse, Gwenaelle ^{[3
]}

Seznec, Vincent ^{[2
]}

Tarascon, Jean-Marie ^{[2
,4
]}

Rosa Palacin, M. ^{[1
]}

机构：

[1] Univ Autonoma Barcelona, Inst Ciencia Mat Barcelona ICMAB CSIC, E-08193 Bellaterra, Catalonia, Spain

[2] Univ Picardie Jules Verne, CNRS, Lab Reactivite & Chim Solides, UMR6007, F-80039 Amiens, France

[3] Univ Paris 06, CNRS, IMPMC, UMR 7590, F-75252 Paris 05, France

[4] Coll France, F-75005 Paris, France

来源：

CHEMISTRY OF MATERIALS | 2011年 / 23卷 / 18期

关键词：

sodium intercalation; sodium ion batteries; layered titanate; Na2Ti3O7; CRYSTAL-STRUCTURE; INTERCALATION; LI; NA; TITANATES; NAXCOO2; SENSOR; CELLS;

D O I：

10.1021/cm202076g

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Na2Ti3O7 is found to reversibly uptake 2 Na ions per formula unit (200 mA h/g) at an average potential of 0.3 V and is hence a very promising negative electrode material for building sodium ion batteries working at room temperature. © 2011 American Chemical Society.

引用

收藏

页码：4109 / 4111

页数：3

相关论文

共 28 条

[1] INTERCALATION POSITIVE ELECTRODES FOR RECHARGEABLE SODIUM CELLS [J].

ABRAHAM, KM .

SOLID STATE IONICS, 1982, 7 (03) :199-212

[2] Negative electrodes for lithium- and sodium-ion batteries obtained by heat-treatment of petroleum cokes below 1000°C [J].

Alcántara, R ;

Mateos, JMJ ;

Tirado, JL .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2002, 149 (02) :A201-A205

[3] CRYSTAL STRUCTURE OF NA2TI3O7 [J].

ANDERSSON, S ;

WADSLEY, AD .

ACTA CRYSTALLOGRAPHICA, 1961, 14 (12) :1245-&

[4] Building better batteries [J].

Armand, M. ;

Tarascon, J. -M. .

NATURE, 2008, 451 (7179) :652-657

[5] A sodium-ion cell based on the fluorophosphate compound NaVPO4F [J].

Barker, J ;

Saidi, MY ;

Swoyer, JL .

ELECTROCHEMICAL AND SOLID STATE LETTERS, 2003, 6 (01) :A1-A4

[6] BOND-VALENCE PARAMETERS OBTAINED FROM A SYSTEMATIC ANALYSIS OF THE INORGANIC CRYSTAL-STRUCTURE DATABASE [J].

BROWN, ID ;

ALTERMATT, D .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1985, 41 (AUG) :244-247

[7] Beyond Intercalation-Based Li-Ion Batteries: The State of the Art and Challenges of Electrode Materials Reacting Through Conversion Reactions [J].

Cabana, Jordi ;

Monconduit, Laure ;

Larcher, Dominique ;

Rosa Palacin, M. .

ADVANCED MATERIALS, 2010, 22 (35) :E170-E192

[8] Synthesis, structure, and electrochemical Li-ion intercalation properties of Li2Ti3O7 with Na2Ti3O7-type layered structure [J].

Chiba, Kazuki ;

Kijima, Norihito ;

Takahashi, Yasuhiko ;

Idemoto, Yasushi ;

Akimoto, Junji .

SOLID STATE IONICS, 2008, 178 (33-34) :1725-1730

[9] ELECTROCHEMICAL INTERCALATION OF SODIUM IN NAXCOO2 BRONZES [J].

DELMAS, C ;

BRACONNIER, JJ ;

FOUASSIER, C ;

HAGENMULLER, P .

SOLID STATE IONICS, 1981, 3-4 (AUG) :165-169

[10] Electrochemical Na-Deintercalation from NaVO2 [J].

Didier, C. ;

Guignard, M. ;

Denage, C. ;

Szajwaj, O. ;

Ito, S. ;

Saadoune, I. ;

Darriet, J. ;

Delmas, C. .

ELECTROCHEMICAL AND SOLID STATE LETTERS, 2011, 14 (05) :A75-A78