Fluorescence properties and energy transfer mechanism of Sm3+ ion in lead telluroborate glasses

被引：71
作者：
Jamalaiah, B. C. [1 ,2 ]
Kumar, M. V. Vijaya [3 ]
Gopal, K. Rama [4 ]
机构：
[1] Sree Vidyanikethan Engn Coll, Dept Phys, Tirupati 517102, Andhra Pradesh, India
[2] Changwon Natl Univ, Dept Phys, Chang Won 641773, South Korea
[3] Rayalaseema Univ, Dept Phys, Kurnool 518002, India
[4] Sri Krishnadevaraya Univ, Dept Phys, Anantapur 515003, Andhra Pradesh, India
来源：
OPTICAL MATERIALS | 2011年 / 33卷 / 11期
关键词：
Lead telluroborate glass; Sm3+ ion; Judd-Ofelt Theory; Fluorescence properties; Energy transfer; OPTICAL-PROPERTIES; BORATE; PHOTOLUMINESCENCE; INTENSITIES; RELAXATION; PARAMETERS; ABSORPTION;
D O I：
10.1016/j.optmat.2011.04.030
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
We report the fluorescence properties of Sm3+-doped lead telluroborate glasses of composition PbF2.TeO2.H3BO3 center dot Sm2O3 as a function of Sm3+ concentration. A Judd-Ofelt scheme was used to determine the intensity parameters and radiative properties of Sm3+ ion. The emission and decay measurements were carried out at 402 nm excitation. Beyond 1.0 mol% Sm3+ concentration, the luminescence quenching is observed. The decay curves of (4)G(5/2) level are well.fitted to a single exponential function. The evaluated radiative properties suggest that the (4)G(5/2) -> H-6(7/2) transition is responsible for reddish-orange luminescence which might be used in the development of visible lasers. (C) 2011 Elsevier B.V. All rights reserved.
引用
收藏
页码：1643 / 1647
页数：5
相关论文
共 32 条
  • [1] Optical properties of Sm3+-doped CaF2 bismuth borate glasses
    Ali, A. A.
    [J]. JOURNAL OF LUMINESCENCE, 2009, 129 (11) : 1314 - 1319
  • [2] CANALEJO M, 1988, PHYS CHEM GLASSES, V29, P187
  • [3] Luminescence and dielectric properties of nano-structured Eu3+:K2O-Nb2O5-SiO2 glass-ceramics
    Chaliha, Reenamoni Saikia
    Annapurna, K.
    Tarafder, Anal
    Tiwari, V. S.
    Gupta, P. K.
    Karmakar, Basudeb
    [J]. SOLID STATE SCIENCES, 2009, 11 (08) : 1325 - 1332
  • [4] Photoluminescence and spectral parameters of Eu3+ in sodium-aluminum-tellurite ceramics
    Chen, B. J.
    Pun, E. Y. B.
    Lin, H.
    [J]. JOURNAL OF ALLOYS AND COMPOUNDS, 2009, 479 (1-2) : 352 - 356
  • [5] FT-IR and Raman study of silver lead borate-based glasses
    Ciceo-Lucacel, Raluca
    Ardelean, Ioan
    [J]. JOURNAL OF NON-CRYSTALLINE SOLIDS, 2007, 353 (18-21) : 2020 - 2024
  • [6] Photoluminescence properties of Sm3+ in LBTAF glasses
    Jamalaiah, B. C.
    Kumar, J. Suresh
    Babu, A. Mohan
    Suhasini, T.
    Moorthy, L. Rama
    [J]. JOURNAL OF LUMINESCENCE, 2009, 129 (04) : 363 - 369
  • [7] Optical properties of Sm3+ ions in zinc and alkali zinc borosulphate glasses
    Jayasankar, CK
    Rukmini, E
    [J]. OPTICAL MATERIALS, 1997, 8 (03) : 193 - 205
  • [8] High-pressure fluorescence study of Sm3+ :lithium fluoroborate glass
    Jayasankar, CK
    Babu, P
    Tröster, T
    Holzapfel, WB
    [J]. JOURNAL OF LUMINESCENCE, 2000, 91 (1-2) : 33 - 39
  • [9] Spectroscopic characteristics of Sm3+-doped alkali fluorophosphate glasses
    Jayasimhadri, M.
    Moorthy, L. R.
    Saleem, S. A.
    Ravikumar, R. V. S. S. N.
    [J]. SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2006, 64 (04) : 939 - 944
  • [10] Spectroscopic properties and Judd-Ofelt analysis of Sm3+ doped lead-germanate-tellurite glasses
    Jayasimhadri, M.
    Cho, Eun-Jin
    Jang, Ki-Wan
    Lee, Ho Sueb
    Kim, Sun Il
    [J]. JOURNAL OF PHYSICS D-APPLIED PHYSICS, 2008, 41 (17)
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