Anion-dependence of the polymeric structures of manganese(II) complexes of N,N′-butylenebis(imidazole)

被引：56

作者：

Ballester, L

Baxter, I

Duncan, PCM

Goodgame, DML ^{[1
]}

Grachvogel, DA

Williams, DJ

机构：

[1] Univ London Imperial Coll Sci Technol & Med, Dept Chem, London SW7 2AY, England

[2] Univ Complutense Madrid, Fac Ciencias Quim, Dept Quim Inorgan 1, E-28040 Madrid, Spain

来源：

POLYHEDRON | 1998年 / 17卷 / 20期

基金：

英国工程与自然科学研究理事会;

关键词：

X-ray structures; polymeric complexes; manganese complexes; bis(imidazole);

D O I：

10.1016/S0277-5387(98)00157-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The preparations and X-band EPR spectra are reported of a series of manganese(II) complexes with N,N'-butylenebis(imidazole) (= BBI) of the types Mn(BBI)(2)X(2) (X = Cl, Br, NO(3), NCS) and [Mn(BBI)(3)]X(2) (X = ClO(4), I). An X-ray crystallographic study on Mn(BBI)(3)Cl(2) (1) shows that each Mn atom is coordinated to four imidazole nitrogen atoms and two chloride ions in a trans-octahedral arrangement and that the BBI ligands link the Mn centres into sheets of contiguous 44-membered rings. X-Ray studies on [Mn(BBI)(3)](ClO(4))(2), and on analogous compounds containing combinations of ClO(4)(-)/PF(6)(-) or ClO(4)(-)/AsF(6)(-) as counter anions, reveal the formation of a family of interpenetrating network structures with anion-dependent cavity sizes. (C) 1998 Elsevier Science Ltd. All rights reserved.

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页码：3613 / 3623

页数：11

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