Silica-supported iron oxide nanoparticles: unexpected catalytic activity in hydrogenation of phenylacetylene

被引：13
|
作者：
Shesterkina, Anastasiya A. [1 ]
Shuvalova, Elena V. [1 ]
Redina, Elena A. [1 ]
Kirichenko, Olga A. [1 ]
Tkachenko, Olga P. [1 ]
Mishin, Igor V. [1 ]
Kustov, Leonid M. [1 ,2 ]
机构：
[1] Russian Acad Sci, ND Zelinsky Inst Organ Chem, Moscow 119991, Russia
[2] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119991, Russia
来源：
MENDELEEV COMMUNICATIONS | 2017年 / 27卷 / 05期
基金：
俄罗斯科学基金会;
关键词：
CORE-SHELL NANOPARTICLES; SELECTIVE HYDROGENATION; PD; FE-PD/SIO2; STABILITY; OXIDATION; LIQUID;
D O I：
10.1016/j.mencom.2017.09.028
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Hydrogenation of phenylacetylene in liquid phase (100-150 degrees C, 6-20 bar H-2) over FeOx/SiO2 catalysts prepared by thermal decomposition of ammonium trioxalatoferrate affords styrene with selectivities 70-80% depending on temperature and pressure.
引用
收藏
页码：512 / 514
页数：3
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