RETRACTED: Vapor-Liquid Equilibria and Density Measurement for Binary Mixtures of Benzene plus Nonane, Methylbenzene plus 1,2-Dimethylbenzene, 1,3-Dimethylbenzene plus 2,3,4,5-Tetrahydrothiophene-1,1-dioxide (Sulfolane), 1,2-Dimethylbenzene plus Sulfolane, 1,2-Dimethylbenzene plus N-Methylformamide (NMF), 1,3-Dimethylbenzene plus NMF, and 1,4-Dimethylbenzene plus NMF from (333.15 to 353.15) K at Vacuum Conditions (Retracted article. See vol. 56, pg. 3714, 2011)

被引:7
作者
Chen, Wei-Kuan [1 ]
Ko, Jing-Wei [2 ]
Chang, Chieh-Ming J. [1 ]
机构
[1] Natl Chung Hsing Univ, Dept Chem Engn, Taichung 402, Taiwan
[2] Res Inst, Proc Res Dept Refining & Manufacturing, Chiayi 600, Taiwan
关键词
AROMATIC-HYDROCARBONS; M-XYLENE; SYSTEMS; TOLUENE; WATER; EXPRESSION; VOLUMES; ENERGY; HEXANE;
D O I
10.1021/je100517z
中图分类号
O414.1 [热力学];
学科分类号
摘要
Vapor-liquid equilibria at (333.15, 343.15, and 353.15) K for seven binary mixtures of benzene + nonane, methylbenzene + 1,2-dimethylbenzene, 1,3-dimethylbenzene + 2,3,4,5-tetrahydrothiophene-1, 1-dioxide, 1,2-dimethylbenzene + 2,3,4,5-tetrahydrothiophene-1,1-dioxide, 1,2-dimethylbenzene + N-methylformamide (NMF), 1,3-dimethylbenzene + NMF. and 1,4-dimethylbenzene + NMF have been obtained at pressures ranging from (0.01 to 101.3) kPa. The Wilson, nonrandom two-liquid (NRTL), and universal quasichemical (UNIQUAC) activity coefficient models have been employed to correlate experimental data to find intermolecular parameters. The nonideal behavior of the vapor phase has been considered by using the Peng-Robinson equation of state in calculating the vapor mole fraction. Liquid and vapor densities were measured by using two vibrating tube densitometers to determine liquid excess molar volumes. Six systems of benzene + nonane. 1,3-dimethylbenzene + 2,3,4,5-tetrahydrothiophene-1, 1-dioxide, 1,2-dimethylbenzene + 2,3,4,5-tetrahydrothiophene-1,1-dioxide. 1,2-dimethylbenzene + NMF, 1,3-dimethylbenzene + NMF, and 1,4-dimethylbenzene + NMF mixtures present large positive deviations from the ideal solution and belong to endothermic mixtures because their excess Gibbs energies are positive. Only one system of the methylbenzene + 1,2-dimethylbenzene mixture may present a slight exothermic mixing deviation from the ideal solution. Temperature-dependent intermolecular parameters in the three models were obtained in this study.
引用
收藏
页码:4352 / 4361
页数:10
相关论文
共 26 条
[1]   STATISTICAL THERMODYNAMICS OF LIQUID-MIXTURES - NEW EXPRESSION FOR EXCESS GIBBS ENERGY OF PARTLY OR COMPLETELY MISCIBLE SYSTEMS [J].
ABRAMS, DS ;
PRAUSNITZ, JM .
AICHE JOURNAL, 1975, 21 (01) :116-128
[2]   Experimental densities, refractive indices, and speeds of sound of 12 binary mixtures containing alkanes and aromatic compounds at T=313.15 K [J].
Calvar, Noelia ;
Gomez, Elena ;
Gonzalez, Begona ;
Dominguez, Angeles .
JOURNAL OF CHEMICAL THERMODYNAMICS, 2009, 41 (08) :939-944
[3]   High-pressure densities and P-T-x-y diagrams for carbon dioxide plus linalool and carbon dioxide plus limonene [J].
Chang, CMJ ;
Chen, CC .
FLUID PHASE EQUILIBRIA, 1999, 163 (01) :119-126
[4]   Vapor-liquid equilibria and densities of CO2 with four unsaturated fatty acid esters at elevated pressures [J].
Chang, CMJ ;
Lee, MS ;
Li, BC ;
Chen, PY .
FLUID PHASE EQUILIBRIA, 2005, 233 (01) :56-65
[5]   Vapor-liquid equilibria and density measurement for binary mixtures of o-xylene plus NMF, m-xylene plus NMF and p-xylene + NMF at 333.15 K, 343.15 K and 353.15 K from 0 kPa to 101.3 kPa [J].
Chen, Wei-Kuan ;
Lee, Kun-Jung ;
Chang, Chieh-Ming J. ;
Ko, Jing-Wei ;
Lee, Liang-Sun .
FLUID PHASE EQUILIBRIA, 2010, 291 (01) :40-47
[6]   Vapor-liquid equilibria and density measurement for binary mixtures of toluene, benzene, o-xylene, m-xylene, sulfolane and nonane at 333.15 K and 353.15 K [J].
Chen, Wei-Kuan ;
Lee, Kun-Jung ;
Ko, Jing-Wei ;
Chang, Chieh-Ming J. ;
Hsiang, Daina ;
Lee, Liang-Sun .
FLUID PHASE EQUILIBRIA, 2010, 287 (02) :126-133
[7]   Vapor-liquid equilibria of binary mixtures containing sulfolane [J].
Domanska, U ;
Sporzynski, A ;
Moollan, WC ;
Letcher, TM .
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1996, 41 (03) :624-628
[8]   Vapor-liquid equilibria for four binary systems at 363.15 K:: N-methylformamide plus hexane, plus benzene, plus chlorobenzene, and plus acetonitrile [J].
Harris, RA ;
Wittig, R ;
Gmehling, J ;
Letcher, TM ;
Ramjugernath, D ;
Raal, JD .
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2003, 48 (02) :341-343
[9]  
*INV PROC SYST INC, 2006, SIM4ME PRO 2 PROVISI
[10]   Measurement and correlation of (vapor plus liquid) equilibria for the {2-propoxyethanol (C3E1) + n-hexane} and the {2-propoxyethanol (C3E1) + n-heptane} systems [J].
Jang, Sunghyun ;
Shin, Moon Sam ;
Lee, Yongjin ;
Kim, Hwayong .
JOURNAL OF CHEMICAL THERMODYNAMICS, 2009, 41 (01) :51-55