Spectroscopic properties of HoAl3(BO3)4 single crystal

被引:19
作者
Ikonnikov, D. A. [1 ]
Malakhovskii, A. V. [2 ]
Sukhachev, A. L. [2 ]
Temerov, V. L. [2 ]
Krylov, A. S. [2 ]
Bovina, A. F. [2 ]
Aleksandrovsky, A. S. [2 ]
机构
[1] Siberian Fed Univ, Krasnoyarsk, Russia
[2] Russian Acad Sci, LV Kirensky Phys Inst, Siberian Branch, Krasnoyarsk 660036, Russia
基金
俄罗斯基础研究基金会;
关键词
Absorption; Luminescence; Holmium; Huntite; Judd-Ofelt; OPTICAL-PROPERTIES; HO3+ IONS; ABSORPTION; INTENSITIES; EMISSION; SPECTRA; LUMINESCENCE; PARAMETERS; GROWTH; TM3+;
D O I
10.1016/j.optmat.2014.05.036
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The Judd-Ofelt theory has been applied to analyze absorption spectra of Ho3+ ion in HoAl3(BO3)(4) measured in spectral range 300-700 nm at room temperature. The Judd-Ofelt spectroscopic parameters have been determined as: ohm(2) = 18.87 x 10(-20) cm(2), ohm(4) = 17.04 x 10(-20) cm(2), ohm(6) = 9.21 x 10(-20) cm(2). These parameters have been used to calculate radiative lifetimes and branching ratios of the luminescence manifolds. Three luminescent bands were found in the spectral range 450-700 nm ascribed to transitions from the F-5(5), (F-5(4), S-5(2)) and K-3(8) states to the ground state I-5(8). Experimental intensities of these luminescence transitions were compared with those calculated by using Judd-Ofelt theory and the system of kinetic equations for populations of starting luminescing states. Probabilities of radiativeless transitions were evaluated from this comparison. (C) 2014 Elsevier B.V. All rights reserved.
引用
收藏
页码:257 / 261
页数:5
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