Tuning of ruthenium N-heterocyclic carbene catalysts for ATRP

被引：88

作者：

Delaude, L ^{[1
]}

Delfosse, S ^{[1
]}

Richel, A ^{[1
]}

Demonceau, A ^{[1
]}

Noels, AF ^{[1
]}

机构：

[1] Univ Liege, Macromol Chem & Organ Catalysis Lab, B-4000 Liege, Belgium

来源：

CHEMICAL COMMUNICATIONS | 2003年 / 13期

关键词：

D O I：

10.1039/b301733h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Depending on the substituents, R-1 and R-2, ruthenium(II) - p-cymene complexes bearing N-heterocyclic carbene ligands are either efficient catalysts for the well-controlled atom transfer radical polymerisation of methyl methacrylate and styrene, or promote a redox-initiated free-radical process.

引用

页码：1526 / 1527

页数：2

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