Microcapsulated epoxy resin with nanosilica-urea formaldehyde composite shell

In this study, the epoxy microcapsules with the nanosilica (0, 1, 2, and 3 wt %)-urea formaldehyde composite shell were synthesized and then characterized by optical microscope (OM), field emission scanning electron microscope (FESEM), Fourier-transform infrared spectroscopy (FT-IR), and thermogravimetric analysis. According to the OM analysis, the without nanosilica microcapsules had the semitransparent structures and equal size distributions. Also, the formation of the microcapsule clusters and rupturing microcapsules in the sample containing 3 wt % nanosilica were observed by OM method. The FESEM analysis showed that without nanosilica, microcapsules had a smooth surface, whereas by increasing the percentage of nanosilica up to 2 wt %, the surface roughness was enhanced. It was also observed that on the surface of the microcapsules without nanosilica, two size ranges of the submicrocapsules with the average diameters of 1.12 mu m and 208 nm were formed. By adding 1 wt % nanosilica, three size ranges of submicrocapsules were formed, with the average size of 2.63 mu m, 824 and 179 nm. The interesting phenomena in the microcapsules containing 2 and 3 wt % nanosilica were the packing submicrocapsules with the polymeric shell and the formation of the microcapsule clusters, respectively. (c) 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2020, 137, 48580.